Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa- 2,5-dien-1-ones into 3,4-dimethylphenol
Publication type: Journal Article
Publication date: 2009-02-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Electrochemical behavior of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones and 2,6-dibromo-4,4-dimethylcyclohexa-2,5-dien-1-one was studied. Reductive dehalogenation of cyclohexa-2,5-dien-1-ones having a halogen atom at the neopentyl-like carbon atom gives the corresponding carbanion which undergoes anionic cyclopropyl-allyl rearrangement with subsequent addition of proton to form 3,4-dimethylphenol.
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Gavrilova G. V. et al. Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa- 2,5-dien-1-ones into 3,4-dimethylphenol // Russian Journal of General Chemistry. 2009. Vol. 79. No. 2. pp. 264-268.
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Gavrilova G. V., Moiseeva A. A., Beloglazkina E. K., Gavrilov A., Zyk N. V. Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa- 2,5-dien-1-ones into 3,4-dimethylphenol // Russian Journal of General Chemistry. 2009. Vol. 79. No. 2. pp. 264-268.
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TY - JOUR
DO - 10.1134/S1070363209020169
UR - http://link.springer.com/10.1134/S1070363209020169
TI - Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa- 2,5-dien-1-ones into 3,4-dimethylphenol
T2 - Russian Journal of General Chemistry
AU - Gavrilova, G V
AU - Moiseeva, A A
AU - Beloglazkina, E K
AU - Gavrilov, A.A.
AU - Zyk, N. V.
PY - 2009
DA - 2009/02/01
PB - Pleiades Publishing
SP - 264-268
IS - 2
VL - 79
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2009_Gavrilova,
author = {G V Gavrilova and A A Moiseeva and E K Beloglazkina and A.A. Gavrilov and N. V. Zyk},
title = {Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa- 2,5-dien-1-ones into 3,4-dimethylphenol},
journal = {Russian Journal of General Chemistry},
year = {2009},
volume = {79},
publisher = {Pleiades Publishing},
month = {feb},
url = {http://link.springer.com/10.1134/S1070363209020169},
number = {2},
pages = {264--268},
doi = {10.1134/S1070363209020169}
}
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Gavrilova, G. V., et al. āElectrochemically induced transformation of 4-halomethyl-4-methylcyclohexa- 2,5-dien-1-ones into 3,4-dimethylphenol.ā Russian Journal of General Chemistry, vol. 79, no. 2, Feb. 2009, pp. 264-268. http://link.springer.com/10.1134/S1070363209020169.
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