Formation of palladium(II) complex with triarylphosphine ligand on the surface of gold electrode modified with di(11-hydroxyundecyl)disulfide. Cyclic voltammetry study
Publication type: Journal Article
Publication date: 2010-02-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Using the method of cyclic voltammetry the possibility of formation of the Pd(II) complex with triarylphosphine ligand on the gold electrode surface is shown resulting from the following sequence of reactions: (1) formation of the self-organized monolayer (SOM) of di(11-mercaptoundecyl)disulfide on the Au surface; (2) esterification of terminal hydroxy groups of the formed SOM with diphenyl(p-carboxyphenyl) phosphine; (3) formation of the complex compound fixed on the surface by treatment of the modified electrode with solution of PdCl2 in CH3CN. The possibility of electrocatalytic reduction of iodobenzene on the gold electrode with participation of the obtained Pd(II) complex is demonstrated.
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Beloglazkina E. K. et al. Formation of palladium(II) complex with triarylphosphine ligand on the surface of gold electrode modified with di(11-hydroxyundecyl)disulfide. Cyclic voltammetry study // Russian Journal of General Chemistry. 2010. Vol. 80. No. 2. pp. 227-231.
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Beloglazkina E. K., Mazhuga A. G., Rakhimov R. D., Zyk N. V. Formation of palladium(II) complex with triarylphosphine ligand on the surface of gold electrode modified with di(11-hydroxyundecyl)disulfide. Cyclic voltammetry study // Russian Journal of General Chemistry. 2010. Vol. 80. No. 2. pp. 227-231.
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TY - JOUR
DO - 10.1134/S1070363210020064
UR - http://link.springer.com/10.1134/S1070363210020064
TI - Formation of palladium(II) complex with triarylphosphine ligand on the surface of gold electrode modified with di(11-hydroxyundecyl)disulfide. Cyclic voltammetry study
T2 - Russian Journal of General Chemistry
AU - Beloglazkina, E K
AU - Mazhuga, A G
AU - Rakhimov, R D
AU - Zyk, N. V.
PY - 2010
DA - 2010/02/01
PB - Pleiades Publishing
SP - 227-231
IS - 2
VL - 80
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2010_Beloglazkina,
author = {E K Beloglazkina and A G Mazhuga and R D Rakhimov and N. V. Zyk},
title = {Formation of palladium(II) complex with triarylphosphine ligand on the surface of gold electrode modified with di(11-hydroxyundecyl)disulfide. Cyclic voltammetry study},
journal = {Russian Journal of General Chemistry},
year = {2010},
volume = {80},
publisher = {Pleiades Publishing},
month = {feb},
url = {http://link.springer.com/10.1134/S1070363210020064},
number = {2},
pages = {227--231},
doi = {10.1134/S1070363210020064}
}
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Beloglazkina, E. K., et al. āFormation of palladium(II) complex with triarylphosphine ligand on the surface of gold electrode modified with di(11-hydroxyundecyl)disulfide. Cyclic voltammetry study.ā Russian Journal of General Chemistry, vol. 80, no. 2, Feb. 2010, pp. 227-231. http://link.springer.com/10.1134/S1070363210020064.
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