Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5- dien-1-one
Publication type: Journal Article
Publication date: 2014-06-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
The properties of 4-methyl-4-(trichloromethyl)cyclohexa-2,5-dien-1-one which contains the trichloromethyl substituent at a quaternary carbon atom have been studied by cyclic voltammetry, rotating disk electrode voltammetry, and preparative electrolysis. Reductive dehalogenation involves initial two-electron reductive elimination of one of the geminal chlorine atoms followed by consecutive addition of proton, simultaneous elimination of the two residual halogen atoms to form carbene, and rearrangement of cyclohexadienone into the corresponding 4-methylcyclohepta-2,4,6-trien-1-one.
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Moiseeva A. A. et al. Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5- dien-1-one // Russian Journal of General Chemistry. 2014. Vol. 84. No. 6. pp. 1074-1078.
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Moiseeva A. A., Gavrilova G. V., Vykhodtseva L., Nikolaeva S., Krutko D. P., Beloglazkina E. K. Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5- dien-1-one // Russian Journal of General Chemistry. 2014. Vol. 84. No. 6. pp. 1074-1078.
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TY - JOUR
DO - 10.1134/S1070363214060036
UR - http://link.springer.com/10.1134/S1070363214060036
TI - Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5- dien-1-one
T2 - Russian Journal of General Chemistry
AU - Moiseeva, A A
AU - Gavrilova, G V
AU - Vykhodtseva, L.N
AU - Nikolaeva, S.N.
AU - Krutko, D P
AU - Beloglazkina, E K
PY - 2014
DA - 2014/06/01
PB - Pleiades Publishing
SP - 1074-1078
IS - 6
VL - 84
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2014_Moiseeva,
author = {A A Moiseeva and G V Gavrilova and L.N Vykhodtseva and S.N. Nikolaeva and D P Krutko and E K Beloglazkina},
title = {Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5- dien-1-one},
journal = {Russian Journal of General Chemistry},
year = {2014},
volume = {84},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1070363214060036},
number = {6},
pages = {1074--1078},
doi = {10.1134/S1070363214060036}
}
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MLA
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Moiseeva, A. A., et al. “Electrochemical reduction of 4-methyl-4-(trichloromethyl)cyclohexa-2,5- dien-1-one.” Russian Journal of General Chemistry, vol. 84, no. 6, Jun. 2014, pp. 1074-1078. http://link.springer.com/10.1134/S1070363214060036.
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