Reaction of o-aminophenol and o-aminobenzyl alcohol with palladium(II) bis(isocyanide) complexes
Publication type: Journal Article
Publication date: 2016-10-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Reactions of palladium(II) bis-isocyanide complexes cis-[PdCl2(CNR)2] (R = 2,6-Me2C6H3, 2-Me-6-ClC6H3) with an equimolar amount of chelating N,O-binucleophiles, 2-aminophenol and (2-aminophenyl)-methanol, in acetonitrile at room temperature in 24 h selectively afforded the corresponding open-chain monocarbene complexes. The complexation involved one isocyanide ligand and amino group of the aromatic amine. Neither bis(carbene) complexes (in the reactions with 4 equiv of the nucleophile under harsh conditions) nor C,O-chelate structures were detected. The isolated complexes were characterized by elemental analyses, IR, NMR, and mass spectra, and X-ray diffraction data.
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Kinzhalov M. A. et al. Reaction of o-aminophenol and o-aminobenzyl alcohol with palladium(II) bis(isocyanide) complexes // Russian Journal of General Chemistry. 2016. Vol. 86. No. 10. pp. 2350-2355.
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Kinzhalov M. A., Starova G. L., Haukka M., Boyarskii V. P. Reaction of o-aminophenol and o-aminobenzyl alcohol with palladium(II) bis(isocyanide) complexes // Russian Journal of General Chemistry. 2016. Vol. 86. No. 10. pp. 2350-2355.
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TY - JOUR
DO - 10.1134/S1070363216100170
UR - https://doi.org/10.1134/S1070363216100170
TI - Reaction of o-aminophenol and o-aminobenzyl alcohol with palladium(II) bis(isocyanide) complexes
T2 - Russian Journal of General Chemistry
AU - Kinzhalov, M A
AU - Starova, G L
AU - Haukka, M
AU - Boyarskii, V P
PY - 2016
DA - 2016/10/01
PB - Pleiades Publishing
SP - 2350-2355
IS - 10
VL - 86
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2016_Kinzhalov,
author = {M A Kinzhalov and G L Starova and M Haukka and V P Boyarskii},
title = {Reaction of o-aminophenol and o-aminobenzyl alcohol with palladium(II) bis(isocyanide) complexes},
journal = {Russian Journal of General Chemistry},
year = {2016},
volume = {86},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S1070363216100170},
number = {10},
pages = {2350--2355},
doi = {10.1134/S1070363216100170}
}
Cite this
MLA
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Kinzhalov, M. A., et al. “Reaction of o-aminophenol and o-aminobenzyl alcohol with palladium(II) bis(isocyanide) complexes.” Russian Journal of General Chemistry, vol. 86, no. 10, Oct. 2016, pp. 2350-2355. https://doi.org/10.1134/S1070363216100170.
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