Reaction of Methyl (2-Methylidene)-3-oxolup-20(29)-en-28-oate with Dimethyl Trimethylsilyl Phosphite
Publication type: Journal Article
Publication date: 2018-09-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
A method of phosphorylation of pentacyclic triterpenoids derivatives containing an α,β-unsaturated carbonyl fragment in the ring A was described by the example of the reaction of methyl (2-methylidene)-3-oxolup-20(29)-en-28-oate with dimethyl trimethylsilyl phosphite. Methyl 2-dimethoxyphosphorylmethyl-3-oxolup-20(29)-en-28-oate was obtained as two epimers in a 2: 1 ratio in a 70% yield.
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Citations from 2024:
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Tsepaeva O. V. et al. Reaction of Methyl (2-Methylidene)-3-oxolup-20(29)-en-28-oate with Dimethyl Trimethylsilyl Phosphite // Russian Journal of General Chemistry. 2018. Vol. 88. No. 9. pp. 1944-1947.
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Tsepaeva O. V., Nemtarev A. V., Abdullin T. I., Kuznetsova E., Mironov V. F. Reaction of Methyl (2-Methylidene)-3-oxolup-20(29)-en-28-oate with Dimethyl Trimethylsilyl Phosphite // Russian Journal of General Chemistry. 2018. Vol. 88. No. 9. pp. 1944-1947.
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RIS
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TY - JOUR
DO - 10.1134/S1070363218090335
UR - https://doi.org/10.1134/S1070363218090335
TI - Reaction of Methyl (2-Methylidene)-3-oxolup-20(29)-en-28-oate with Dimethyl Trimethylsilyl Phosphite
T2 - Russian Journal of General Chemistry
AU - Tsepaeva, O V
AU - Nemtarev, A V
AU - Abdullin, T I
AU - Kuznetsova, E.V.
AU - Mironov, V F
PY - 2018
DA - 2018/09/01
PB - Pleiades Publishing
SP - 1944-1947
IS - 9
VL - 88
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2018_Tsepaeva,
author = {O V Tsepaeva and A V Nemtarev and T I Abdullin and E.V. Kuznetsova and V F Mironov},
title = {Reaction of Methyl (2-Methylidene)-3-oxolup-20(29)-en-28-oate with Dimethyl Trimethylsilyl Phosphite},
journal = {Russian Journal of General Chemistry},
year = {2018},
volume = {88},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1070363218090335},
number = {9},
pages = {1944--1947},
doi = {10.1134/S1070363218090335}
}
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MLA
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Tsepaeva, O. V., et al. “Reaction of Methyl (2-Methylidene)-3-oxolup-20(29)-en-28-oate with Dimethyl Trimethylsilyl Phosphite.” Russian Journal of General Chemistry, vol. 88, no. 9, Sep. 2018, pp. 1944-1947. https://doi.org/10.1134/S1070363218090335.