Synthesis of New 4,4a-Dihydroxanthones via [4+2]-Cycloaddition Reaction
Publication type: Journal Article
Publication date: 2019-12-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
The effect of electronic properties of substituents in the reactants on the [4+2]-cycloaddition of 3-vinyl-chromen-4-ones (dienes) and N-vinylpyrrolidines (dienophiles) has been studied. The conditions determining the formation of 4,4a-dihydroxanthones or benzophenones as the major products have been found. The aromatization of 4,4a-dihydroxanthones via pyran ring opening has been interpreted by quantum chemical calculations. A wide series of new 4,4a-dihydroxanthone and benzophenone derivatives have been isolated.
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Chernov N. M. et al. Synthesis of New 4,4a-Dihydroxanthones via [4+2]-Cycloaddition Reaction // Russian Journal of General Chemistry. 2019. Vol. 89. No. 12. pp. 2463-2470.
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Chernov N. M., Moroz T. V., Shutov R. V., Kuzmich N. N., Shchegolev A. E., Sopova M. V., Yakovlev I. P. Synthesis of New 4,4a-Dihydroxanthones via [4+2]-Cycloaddition Reaction // Russian Journal of General Chemistry. 2019. Vol. 89. No. 12. pp. 2463-2470.
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RIS
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TY - JOUR
DO - 10.1134/S1070363219120223
UR - https://doi.org/10.1134/S1070363219120223
TI - Synthesis of New 4,4a-Dihydroxanthones via [4+2]-Cycloaddition Reaction
T2 - Russian Journal of General Chemistry
AU - Chernov, N M
AU - Moroz, T V
AU - Shutov, R V
AU - Kuzmich, N. N.
AU - Shchegolev, A E
AU - Sopova, M V
AU - Yakovlev, I P
PY - 2019
DA - 2019/12/01
PB - Pleiades Publishing
SP - 2463-2470
IS - 12
VL - 89
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2019_Chernov,
author = {N M Chernov and T V Moroz and R V Shutov and N. N. Kuzmich and A E Shchegolev and M V Sopova and I P Yakovlev},
title = {Synthesis of New 4,4a-Dihydroxanthones via [4+2]-Cycloaddition Reaction},
journal = {Russian Journal of General Chemistry},
year = {2019},
volume = {89},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1070363219120223},
number = {12},
pages = {2463--2470},
doi = {10.1134/S1070363219120223}
}
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MLA
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Chernov, N. M., et al. “Synthesis of New 4,4a-Dihydroxanthones via [4+2]-Cycloaddition Reaction.” Russian Journal of General Chemistry, vol. 89, no. 12, Dec. 2019, pp. 2463-2470. https://doi.org/10.1134/S1070363219120223.
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