Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties
Тип публикации: Journal Article
Дата публикации: 2021-03-01
scimago Q4
wos Q4
БС2
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Краткое описание
A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.
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Katkova S. A. et al. Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties // Russian Journal of General Chemistry. 2021. Vol. 91. No. 3. pp. 393-400.
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Katkova S. A., Eliseev I. I., Mikherdov A. S., Sokolova E. V., Starova G. L., Kinzhalov M. A. Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties // Russian Journal of General Chemistry. 2021. Vol. 91. No. 3. pp. 393-400.
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TY - JOUR
DO - 10.1134/S1070363221030099
UR - https://doi.org/10.1134/S1070363221030099
TI - Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties
T2 - Russian Journal of General Chemistry
AU - Katkova, S A
AU - Eliseev, I I
AU - Mikherdov, A S
AU - Sokolova, E. V.
AU - Starova, G L
AU - Kinzhalov, M A
PY - 2021
DA - 2021/03/01
PB - Pleiades Publishing
SP - 393-400
IS - 3
VL - 91
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2021_Katkova,
author = {S A Katkova and I I Eliseev and A S Mikherdov and E. V. Sokolova and G L Starova and M A Kinzhalov},
title = {Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties},
journal = {Russian Journal of General Chemistry},
year = {2021},
volume = {91},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S1070363221030099},
number = {3},
pages = {393--400},
doi = {10.1134/S1070363221030099}
}
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Katkova, S. A., et al. “Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties.” Russian Journal of General Chemistry, vol. 91, no. 3, Mar. 2021, pp. 393-400. https://doi.org/10.1134/S1070363221030099.
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