volume 91 issue 3 pages 393-400

Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties

S A Katkova 1
I I Eliseev 1
A S Mikherdov 1
E. V. Sokolova 1
G L Starova 1
Publication typeJournal Article
Publication date2021-03-01
scimago Q4
wos Q4
SJR0.179
CiteScore1.4
Impact factor0.8
ISSN10703632, 16083350
General Chemistry
Abstract
A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.
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Katkova S. A. et al. Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties // Russian Journal of General Chemistry. 2021. Vol. 91. No. 3. pp. 393-400.
GOST all authors (up to 50) Copy
Katkova S. A., Eliseev I. I., Mikherdov A. S., Sokolova E. V., Starova G. L., Kinzhalov M. A. Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties // Russian Journal of General Chemistry. 2021. Vol. 91. No. 3. pp. 393-400.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1070363221030099
UR - https://doi.org/10.1134/S1070363221030099
TI - Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties
T2 - Russian Journal of General Chemistry
AU - Katkova, S A
AU - Eliseev, I I
AU - Mikherdov, A S
AU - Sokolova, E. V.
AU - Starova, G L
AU - Kinzhalov, M A
PY - 2021
DA - 2021/03/01
PB - Pleiades Publishing
SP - 393-400
IS - 3
VL - 91
SN - 1070-3632
SN - 1608-3350
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2021_Katkova,
author = {S A Katkova and I I Eliseev and A S Mikherdov and E. V. Sokolova and G L Starova and M A Kinzhalov},
title = {Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties},
journal = {Russian Journal of General Chemistry},
year = {2021},
volume = {91},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S1070363221030099},
number = {3},
pages = {393--400},
doi = {10.1134/S1070363221030099}
}
MLA
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Katkova, S. A., et al. “Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties.” Russian Journal of General Chemistry, vol. 91, no. 3, Mar. 2021, pp. 393-400. https://doi.org/10.1134/S1070363221030099.