First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2
Publication type: Journal Article
Publication date: 2015-11-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
New method was developed of the synthesis of 2-phenyl(alkyl, benzyl, phenoxy)-1-chloroboriranes via reaction of α-olefins with BCl3·SMe2 catalyzed by Cp2TiCl2. The method is based on the boracyclopropanes (boriranes) formation resulting from transmetallation of titanacyclopropanes arising from the reaction of α-olefins with Cp2TiCl2. The calculations were fulfilled of thermodynamic and activation parameters of possible reaction routes.
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Total citations:
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Citations from 2024:
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(17.64%)
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Khusainova L. I. et al. First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2 // Russian Journal of Organic Chemistry. 2015. Vol. 51. No. 11. pp. 1517-1523.
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Khusainova L. I., Khafizova L. O., Tyumkina T. V., Dzhemilev U. M. First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2 // Russian Journal of Organic Chemistry. 2015. Vol. 51. No. 11. pp. 1517-1523.
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TY - JOUR
DO - 10.1134/S1070428015110019
UR - https://doi.org/10.1134/S1070428015110019
TI - First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2
T2 - Russian Journal of Organic Chemistry
AU - Khusainova, L I
AU - Khafizova, L O
AU - Tyumkina, T V
AU - Dzhemilev, U M
PY - 2015
DA - 2015/11/01
PB - Pleiades Publishing
SP - 1517-1523
IS - 11
VL - 51
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2015_Khusainova,
author = {L I Khusainova and L O Khafizova and T V Tyumkina and U M Dzhemilev},
title = {First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2},
journal = {Russian Journal of Organic Chemistry},
year = {2015},
volume = {51},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1070428015110019},
number = {11},
pages = {1517--1523},
doi = {10.1134/S1070428015110019}
}
Cite this
MLA
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Khusainova, L. I., et al. “First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2.” Russian Journal of Organic Chemistry, vol. 51, no. 11, Nov. 2015, pp. 1517-1523. https://doi.org/10.1134/S1070428015110019.