Russian Journal of Organic Chemistry, volume 54, issue 9, pages 1350-1357
New -Conjugated Ferrocenyl-Substituted Heterocyclic Systems Containing Electron-Deficient Aromatic Nitrogen Heterocycles
Antufeva A D
1
,
Dmitriev M V
2
,
Maiorova O A
1
,
Mokrushin I G
2
,
Galeev A R
2
,
Shklyaeva E V
2, 3
,
Abashev G. G.
1, 2
Publication type: Journal Article
Publication date: 2018-09-01
Journal:
Russian Journal of Organic Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.8
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
A series of ferrocenyl-substituted methyl ketones and chalcones were synthesized and converted to unsymmetrical 4,6-disubstituted pyrimidin-2-amines and 2-(1H-pyrrol-1-yl)pyrimidines in which the ferrocene fragment is separated from the pyrimidine ring by π-deficient (pyridine) or π-excessive (thiophene) heterocycle. The forbidden band gap of the obtained compounds was determined on the basis of their UV spectra ($$E_{\text{g}}^{\text{opt}}$$Egopt = 1.75‒2.36 eV), and their electrochemical properties were studied. The presence of a thiophene ring between the ferrocene and pyrimidine fragments reduces the redox potential of the ferrocene fragment (20‒30 mV), whereas pyridine spacer between the ferrocene and pyrimidine fragment increases the redox potential of the ferrocene fragment by more than 100 mV.
Citations by journals
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1
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Asian Journal of Organic Chemistry
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Asian Journal of Organic Chemistry
1 publication, 50%
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RSC Advances
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RSC Advances
1 publication, 50%
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1
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Citations by publishers
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1
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Wiley
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Wiley
1 publication, 50%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 50%
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1
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Antufeva A. D. et al. New -Conjugated Ferrocenyl-Substituted Heterocyclic Systems Containing Electron-Deficient Aromatic Nitrogen Heterocycles // Russian Journal of Organic Chemistry. 2018. Vol. 54. No. 9. pp. 1350-1357.
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Antufeva A. D., Dmitriev M. V., Maiorova O. A., Mokrushin I. G., Galeev A. R., Shklyaeva E. V., Abashev G. G. New -Conjugated Ferrocenyl-Substituted Heterocyclic Systems Containing Electron-Deficient Aromatic Nitrogen Heterocycles // Russian Journal of Organic Chemistry. 2018. Vol. 54. No. 9. pp. 1350-1357.
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TY - JOUR
DO - 10.1134/S1070428018090142
UR - https://doi.org/10.1134%2FS1070428018090142
TI - New -Conjugated Ferrocenyl-Substituted Heterocyclic Systems Containing Electron-Deficient Aromatic Nitrogen Heterocycles
T2 - Russian Journal of Organic Chemistry
AU - Antufeva, A D
AU - Dmitriev, M V
AU - Maiorova, O A
AU - Mokrushin, I G
AU - Galeev, A R
AU - Shklyaeva, E V
AU - Abashev, G. G.
PY - 2018
DA - 2018/09/01 00:00:00
PB - Pleiades Publishing
SP - 1350-1357
IS - 9
VL - 54
SN - 1070-4280
SN - 1608-3393
ER -
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@article{2018_Antufeva,
author = {A D Antufeva and M V Dmitriev and O A Maiorova and I G Mokrushin and A R Galeev and E V Shklyaeva and G. G. Abashev},
title = {New -Conjugated Ferrocenyl-Substituted Heterocyclic Systems Containing Electron-Deficient Aromatic Nitrogen Heterocycles},
journal = {Russian Journal of Organic Chemistry},
year = {2018},
volume = {54},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS1070428018090142},
number = {9},
pages = {1350--1357},
doi = {10.1134/S1070428018090142}
}
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MLA
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Antufeva, A. D., et al. “New -Conjugated Ferrocenyl-Substituted Heterocyclic Systems Containing Electron-Deficient Aromatic Nitrogen Heterocycles.” Russian Journal of Organic Chemistry, vol. 54, no. 9, Sep. 2018, pp. 1350-1357. https://doi.org/10.1134%2FS1070428018090142.