Fischer Reaction in the Synthesis of New Triterpene Indoles of the Fusidane Series
Publication type: Journal Article
Publication date: 2022-01-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
The Fischer reaction of 3,11-dioxo derivatives of fusidic acid and its esters with phenylhydrazine chemoselectively occurred at the 3-position with the formation of indole-fused fusidane triterpenoids. The reaction with 3-chlorophenylhydrazine under similar conditions afforded mixtures of isomeric 6- and 4-chloro derivatives at a ratio of 3:2. 2,4-Dinitrophenylhydrazine reacted with the same fusidane diketones to give the corresponding hydrazones at the 3-oxo group. Biological screening of the synthesized compounds revealed derivatives exhibiting a high antibacterial activity against methicillin-resistant Staphylococcus aureus with a minimum inhibitory concentration of ≤0.25 μg/mL.
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Salimova E. V., Parfenova L. V. Fischer Reaction in the Synthesis of New Triterpene Indoles of the Fusidane Series // Russian Journal of Organic Chemistry. 2022. Vol. 58. No. 1. pp. 25-37.
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Salimova E. V., Parfenova L. V. Fischer Reaction in the Synthesis of New Triterpene Indoles of the Fusidane Series // Russian Journal of Organic Chemistry. 2022. Vol. 58. No. 1. pp. 25-37.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1070428022010031
UR - https://doi.org/10.1134/S1070428022010031
TI - Fischer Reaction in the Synthesis of New Triterpene Indoles of the Fusidane Series
T2 - Russian Journal of Organic Chemistry
AU - Salimova, Elena V
AU - Parfenova, Lyudmila V.
PY - 2022
DA - 2022/01/01
PB - Pleiades Publishing
SP - 25-37
IS - 1
VL - 58
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2022_Salimova,
author = {Elena V Salimova and Lyudmila V. Parfenova},
title = {Fischer Reaction in the Synthesis of New Triterpene Indoles of the Fusidane Series},
journal = {Russian Journal of Organic Chemistry},
year = {2022},
volume = {58},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134/S1070428022010031},
number = {1},
pages = {25--37},
doi = {10.1134/S1070428022010031}
}
Cite this
MLA
Copy
Salimova, Elena V., and Lyudmila V. Parfenova. “Fischer Reaction in the Synthesis of New Triterpene Indoles of the Fusidane Series.” Russian Journal of Organic Chemistry, vol. 58, no. 1, Jan. 2022, pp. 25-37. https://doi.org/10.1134/S1070428022010031.