Intermediate particles in the catalysis of radical reactions of chlorohydrocarbons
Publication type: Journal Article
Publication date: 2009-04-01
scimago Q4
SJR: 0.244
CiteScore: 2.6
Impact factor: —
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Abstract
Intermediate products of radical reactions of chlorohydrocarbons catalyzed by copper chloride complexes were synthesized by the photolysis of solutions of [(C4H9)3BzN+]2[CuCl4]2− in chlorobenzene and chloroform at the wavelength corresponding to Cl → Cu charge transfer. It was shown by the EPR method that the products of photolysis were alkyl radicals formed by organic fragments of the quaternary ammonium cation and Cu(II) complexes (supposedly organocopper compounds). The total content of paramagnetic centers decreased. The mechanisms of photoreduction of quaternary ammonium tetrachlorocuprates and possible reasons for the decay of paramagnetic particles were considered.
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GOST
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Golubeva E. N., Lobanov A. V., Kokorin A. I. Intermediate particles in the catalysis of radical reactions of chlorohydrocarbons // Russian Journal of Physical Chemistry B. 2009. Vol. 3. No. 2. pp. 179-184.
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Golubeva E. N., Lobanov A. V., Kokorin A. I. Intermediate particles in the catalysis of radical reactions of chlorohydrocarbons // Russian Journal of Physical Chemistry B. 2009. Vol. 3. No. 2. pp. 179-184.
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RIS
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TY - JOUR
DO - 10.1134/S199079310902002X
UR - https://doi.org/10.1134/S199079310902002X
TI - Intermediate particles in the catalysis of radical reactions of chlorohydrocarbons
T2 - Russian Journal of Physical Chemistry B
AU - Golubeva, E. N.
AU - Lobanov, A. V.
AU - Kokorin, A I
PY - 2009
DA - 2009/04/01
PB - Pleiades Publishing
SP - 179-184
IS - 2
VL - 3
SN - 1990-7931
SN - 1990-7923
ER -
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BibTex (up to 50 authors)
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@article{2009_Golubeva,
author = {E. N. Golubeva and A. V. Lobanov and A I Kokorin},
title = {Intermediate particles in the catalysis of radical reactions of chlorohydrocarbons},
journal = {Russian Journal of Physical Chemistry B},
year = {2009},
volume = {3},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S199079310902002X},
number = {2},
pages = {179--184},
doi = {10.1134/S199079310902002X}
}
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MLA
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Golubeva, E. N., et al. “Intermediate particles in the catalysis of radical reactions of chlorohydrocarbons.” Russian Journal of Physical Chemistry B, vol. 3, no. 2, Apr. 2009, pp. 179-184. https://doi.org/10.1134/S199079310902002X.
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