EPR Diagnostics of D,L-Polylactide Porous Matrices Formed in Supercritical CO2
N A Chumakova
1
,
E. N. Golubeva
1
,
T.A. Ivanova
1
,
N N Vorobieva
2
,
P S Timashev
2, 3
,
V. N. Bagratashvili
2
2
Тип публикации: Journal Article
Дата публикации: 2018-12-01
scimago Q4
БС2
SJR: 0.244
CiteScore: 2.6
Impact factor: —
ISSN: 19907931, 19907923
Physical and Theoretical Chemistry
Краткое описание
The regularities of formation of D,L-polylactide porous matrices in supercritical CO2 environment with simultaneous impregnation with paramagnetic biologically active 4-hydroxy-2,2,6,6-tetramethylpiperidine- 1-oxyl (TEMPOL) was studied using spin probe electron paramagnetic resonance (EPR) and optical microscopy. The dependence of the average and local concentration of a dopant on impregnation conditions was assessed. The resulting matrices meet important requirements for porous materials for tissue engineering. Considering that impregnation of a polymer with a paramagnetic compound makes it possible to study the uniform distribution of a dopant in a sample at macroscopic and microscopic levels and to study a structure of a polymer matrix, EPR spectroscopy is a promising method for studying porous polymeric materials formed under supercritical conditions.
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Chumakova N. A. et al. EPR Diagnostics of D,L-Polylactide Porous Matrices Formed in Supercritical CO2 // Russian Journal of Physical Chemistry B. 2018. Vol. 12. No. 8. pp. 1255-1260.
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Chumakova N. A., Golubeva E. N., Ivanova T., Vorobieva N. N., Timashev P. S., Bagratashvili V. N. EPR Diagnostics of D,L-Polylactide Porous Matrices Formed in Supercritical CO2 // Russian Journal of Physical Chemistry B. 2018. Vol. 12. No. 8. pp. 1255-1260.
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TY - JOUR
DO - 10.1134/S1990793118080031
UR - https://doi.org/10.1134/S1990793118080031
TI - EPR Diagnostics of D,L-Polylactide Porous Matrices Formed in Supercritical CO2
T2 - Russian Journal of Physical Chemistry B
AU - Chumakova, N A
AU - Golubeva, E. N.
AU - Ivanova, T.A.
AU - Vorobieva, N N
AU - Timashev, P S
AU - Bagratashvili, V. N.
PY - 2018
DA - 2018/12/01
PB - Pleiades Publishing
SP - 1255-1260
IS - 8
VL - 12
SN - 1990-7931
SN - 1990-7923
ER -
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@article{2018_Chumakova,
author = {N A Chumakova and E. N. Golubeva and T.A. Ivanova and N N Vorobieva and P S Timashev and V. N. Bagratashvili},
title = {EPR Diagnostics of D,L-Polylactide Porous Matrices Formed in Supercritical CO2},
journal = {Russian Journal of Physical Chemistry B},
year = {2018},
volume = {12},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1990793118080031},
number = {8},
pages = {1255--1260},
doi = {10.1134/S1990793118080031}
}
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MLA
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Chumakova, N. A., et al. “EPR Diagnostics of D,L-Polylactide Porous Matrices Formed in Supercritical CO2.” Russian Journal of Physical Chemistry B, vol. 12, no. 8, Dec. 2018, pp. 1255-1260. https://doi.org/10.1134/S1990793118080031.
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