Protection of Metals and Physical Chemistry of Surfaces

, volume 48 , issue 6 , pages 656-664

The directional formation and protective effect of self-assembling vinyl siloxane nanolayers on copper surface

M. A. Petrunin

L B Maksaeva

T A Yurasova

E V Terekhova

V A Kotenev

E. N. Kablov

A. Yu. Tsivadze

Publication type: Journal Article

Publication date: 2012-11-15

Pleiades Publishing

Protection of Metals and Physical Chemistry of Surfaces

scimago Q3

wos Q4

SJR: 0.211

CiteScore: 1.7

Impact factor: 0.8

ISSN: 20702051, 2070206X

DOI: 10.1134/S2070205112060081

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

Organic Chemistry

Abstract

With the use of the electrochemical-quartz crystal microbalance technique, scanner-assisted electrochemical reflectometry, and X-ray spectral microanalysis, adsorption of vinyl triethoxysilane on a copper surface from an aqueous solution is studied and the possibilities of directional formation of self-assembling layers and their protective effect in corrosive chloride-containing electrolytes are determined. The greatest protective effect is observed at a thickness of 3.8 molecular layers when the most compact film, which hampers the adsorption of chloride ions and substantially decreases the rate of their interaction with the surface copper atoms, is formed.

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1 citation

Timofeeva Viktoriya

33 publications, 214 citations

h-index: 9

N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

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Petrunin M. A. et al. The directional formation and protective effect of self-assembling vinyl siloxane nanolayers on copper surface // Protection of Metals and Physical Chemistry of Surfaces. 2012. Vol. 48. No. 6. pp. 656-664.

GOST all authors (up to 50) Copy

Petrunin M. A., Maksaeva L. B., Yurasova T. A., Terekhova E. V., Kotenev V. A., Kablov E. N., Tsivadze A. Y. The directional formation and protective effect of self-assembling vinyl siloxane nanolayers on copper surface // Protection of Metals and Physical Chemistry of Surfaces. 2012. Vol. 48. No. 6. pp. 656-664.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S2070205112060081

UR - http://link.springer.com/10.1134/S2070205112060081

TI - The directional formation and protective effect of self-assembling vinyl siloxane nanolayers on copper surface

T2 - Protection of Metals and Physical Chemistry of Surfaces

AU - Petrunin, M. A.

AU - Maksaeva, L B

AU - Yurasova, T A

AU - Terekhova, E V

AU - Kotenev, V A

AU - Kablov, E. N.

AU - Tsivadze, A. Yu.

PY - 2012

DA - 2012/11/15

PB - Pleiades Publishing

SP - 656-664

IS - 6

VL - 48

SN - 2070-2051

SN - 2070-206X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2012_Petrunin,

author = {M. A. Petrunin and L B Maksaeva and T A Yurasova and E V Terekhova and V A Kotenev and E. N. Kablov and A. Yu. Tsivadze},

title = {The directional formation and protective effect of self-assembling vinyl siloxane nanolayers on copper surface},

journal = {Protection of Metals and Physical Chemistry of Surfaces},

year = {2012},

volume = {48},

publisher = {Pleiades Publishing},

month = {nov},

url = {http://link.springer.com/10.1134/S2070205112060081},

number = {6},

pages = {656--664},

doi = {10.1134/S2070205112060081}

}

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Petrunin, M. A., et al. “The directional formation and protective effect of self-assembling vinyl siloxane nanolayers on copper surface.” Protection of Metals and Physical Chemistry of Surfaces, vol. 48, no. 6, Nov. 2012, pp. 656-664. http://link.springer.com/10.1134/S2070205112060081.