volume 49 issue 2 pages 173-180

Heteroleptic triple-decker terbium(III) (porphyrinato) (crownphthalocyaninate) as an efficient receptor of alkaline metal cations

K P Birin
K A Kamarova
Publication typeJournal Article
Publication date2013-03-25
scimago Q3
wos Q4
SJR0.211
CiteScore1.7
Impact factor0.8
ISSN20702051, 2070206X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Organic Chemistry
Abstract
Peculiarities of the interaction between a heteroleptic triple-decker terbium(III) complex of a general type [Br4TPP]Tb[(15C5)4Pc]Tb[(15C5)4Pc] (Tb-TD*, where Br4TPP = 5,10,15,20-tetra-(4-bromophenyl)-porphyrin and (15C5)4 Pc = tetra-(15-crown-5)-phthalocyanine) and potassium cations in different solvents are studied. The interaction between Tb-TD* and potassium acetate is found to proceed via either the supramolecular dimerization of the complex or the inclusion of the cations between the crown-containing molecular decks depending on the polarity of the media. From the analysis of the titration curves, the stability constant of Tb-TD* × 4K+ adduct in a chloroform : methanol = 1 : 1 mixture was estimated. The stability constant of the aggregate was found to exceed the known values of similar compounds by over ten orders.
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Birin K. P. et al. Heteroleptic triple-decker terbium(III) (porphyrinato) (crownphthalocyaninate) as an efficient receptor of alkaline metal cations // Protection of Metals and Physical Chemistry of Surfaces. 2013. Vol. 49. No. 2. pp. 173-180.
GOST all authors (up to 50) Copy
Birin K. P., Kamarova K. A., Gorbunova Y. G., Tsivadze A. Y. Heteroleptic triple-decker terbium(III) (porphyrinato) (crownphthalocyaninate) as an efficient receptor of alkaline metal cations // Protection of Metals and Physical Chemistry of Surfaces. 2013. Vol. 49. No. 2. pp. 173-180.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S2070205113020032
UR - http://link.springer.com/10.1134/S2070205113020032
TI - Heteroleptic triple-decker terbium(III) (porphyrinato) (crownphthalocyaninate) as an efficient receptor of alkaline metal cations
T2 - Protection of Metals and Physical Chemistry of Surfaces
AU - Birin, K P
AU - Kamarova, K A
AU - Gorbunova, Yu. G.
AU - Tsivadze, A. Yu.
PY - 2013
DA - 2013/03/25
PB - Pleiades Publishing
SP - 173-180
IS - 2
VL - 49
SN - 2070-2051
SN - 2070-206X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Birin,
author = {K P Birin and K A Kamarova and Yu. G. Gorbunova and A. Yu. Tsivadze},
title = {Heteroleptic triple-decker terbium(III) (porphyrinato) (crownphthalocyaninate) as an efficient receptor of alkaline metal cations},
journal = {Protection of Metals and Physical Chemistry of Surfaces},
year = {2013},
volume = {49},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S2070205113020032},
number = {2},
pages = {173--180},
doi = {10.1134/S2070205113020032}
}
MLA
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MLA Copy
Birin, K. P., et al. “Heteroleptic triple-decker terbium(III) (porphyrinato) (crownphthalocyaninate) as an efficient receptor of alkaline metal cations.” Protection of Metals and Physical Chemistry of Surfaces, vol. 49, no. 2, Mar. 2013, pp. 173-180. http://link.springer.com/10.1134/S2070205113020032.