Protection of Metals and Physical Chemistry of Surfaces

, том 49 , издание 6 , страницы 655-661

Adsorption of alkoxysilanes on aluminum surface from aqueous solutions

M. A. Petrunin ¹

L B Maksaeva ¹

T A Yurasova ¹

E V Terekhova ¹

V A Kotenev ¹

A. Yu. Tsivadze ¹

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Frumkin Institute of Physical Chemistry and electrochemistry, Russian Academy of Sciences, Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2013-11-07

Pleiades Publishing

Protection of Metals and Physical Chemistry of Surfaces

scimago Q3

wos Q4

БС2

SJR: 0.211

CiteScore: 1.7

Impact factor: 0.8

ISSN: 20702051, 2070206X

DOI: 10.1134/S2070205113060117

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

Organic Chemistry

Краткое описание

Adsorption of vinyltriethoxysilane and γ-aminopropyltriethoxysilane on the surface of aluminum from an aqueous solution is studied with the use of a quartz-crystal microbalance. Upon adsorption of silanes, adsorbed water is found to be displaced from the surface. For the interpretation of adsorption data, Langmuir, Brunauer-Emmett-Teller, Flory-Huggins, multisite Langmuir, Temkin, Frumkin, and Freundlich adsorption isotherms were used. The surface orientation of adsorbed molecules is determined. The heat of adsorption of silanes is calculated in different ways. Silanes are found to be chemisorbed on the surface of aluminum.

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Petrunin M. A. et al. Adsorption of alkoxysilanes on aluminum surface from aqueous solutions // Protection of Metals and Physical Chemistry of Surfaces. 2013. Vol. 49. No. 6. pp. 655-661.

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Petrunin M. A., Maksaeva L. B., Yurasova T. A., Terekhova E. V., Kotenev V. A., Tsivadze A. Y. Adsorption of alkoxysilanes on aluminum surface from aqueous solutions // Protection of Metals and Physical Chemistry of Surfaces. 2013. Vol. 49. No. 6. pp. 655-661.

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TY - JOUR

DO - 10.1134/S2070205113060117

UR - http://link.springer.com/10.1134/S2070205113060117

TI - Adsorption of alkoxysilanes on aluminum surface from aqueous solutions

T2 - Protection of Metals and Physical Chemistry of Surfaces

AU - Petrunin, M. A.

AU - Maksaeva, L B

AU - Yurasova, T A

AU - Terekhova, E V

AU - Kotenev, V A

AU - Tsivadze, A. Yu.

PY - 2013

DA - 2013/11/07

PB - Pleiades Publishing

SP - 655-661

IS - 6

VL - 49

SN - 2070-2051

SN - 2070-206X

ER -

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@article{2013_Petrunin,

author = {M. A. Petrunin and L B Maksaeva and T A Yurasova and E V Terekhova and V A Kotenev and A. Yu. Tsivadze},

title = {Adsorption of alkoxysilanes on aluminum surface from aqueous solutions},

journal = {Protection of Metals and Physical Chemistry of Surfaces},

year = {2013},

volume = {49},

publisher = {Pleiades Publishing},

month = {nov},

url = {http://link.springer.com/10.1134/S2070205113060117},

number = {6},

pages = {655--661},

doi = {10.1134/S2070205113060117}

}

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Petrunin, M. A., et al. “Adsorption of alkoxysilanes on aluminum surface from aqueous solutions.” Protection of Metals and Physical Chemistry of Surfaces, vol. 49, no. 6, Nov. 2013, pp. 655-661. http://link.springer.com/10.1134/S2070205113060117.