Protection of Metals and Physical Chemistry of Surfaces

, volume 50 , issue 6 , pages 784-791

The effect of self-organizing vinyl siloxane nanolayers on the corrosion behavior of aluminum in neutral chloride-containing solutions

M. A. Petrunin

L B Maksaeva

T A Yurasova

E V Terekhova

M A Maleeva

A. A. Shcherbina

V A Kotenev

E. N. Kablov

A. Yu. Tsivadze

Publication type: Journal Article

Publication date: 2014-11-04

Pleiades Publishing

Protection of Metals and Physical Chemistry of Surfaces

scimago Q3

wos Q4

SJR: 0.211

CiteScore: 1.7

Impact factor: 0.8

ISSN: 20702051, 2070206X

DOI: 10.1134/S2070205114060161

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

Organic Chemistry

Abstract

The methods of quartz crystal microbalance, atomic force microscopy (AFM), scanning electron microscopy (SEM), Fourier-transform IR spectroscopy, and X-ray structural microanalysis were is used to show that adsorption of vinyl silane on an aluminum surface from an aqueous solution results in formation of a uniform, self-organizing protective vinyl siloxane nanolayer covalently bound with surface metal groups. Its thickness can be controlled by variation of application conditions. The effect of a vinyl siloxane nanolayer on dissolution of aluminum is studied in chloride-containing solutions. It is found that an ordered vinyl siloxane nanolayer with a thickness of up to 5 molecular layers causes efficient inhibition of uniform and local corrosion of aluminum. It is shown that the vinyl siloxane nanolayer is preserved on the surface of aluminum after 10 days of corrosion tests, which indicates its stability at exposure to water and corrosive components.

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Petrunin M. A. et al. The effect of self-organizing vinyl siloxane nanolayers on the corrosion behavior of aluminum in neutral chloride-containing solutions // Protection of Metals and Physical Chemistry of Surfaces. 2014. Vol. 50. No. 6. pp. 784-791.

GOST all authors (up to 50) Copy

Petrunin M. A., Maksaeva L. B., Yurasova T. A., Terekhova E. V., Maleeva M. A., Shcherbina A. A., Kotenev V. A., Kablov E. N., Tsivadze A. Y. The effect of self-organizing vinyl siloxane nanolayers on the corrosion behavior of aluminum in neutral chloride-containing solutions // Protection of Metals and Physical Chemistry of Surfaces. 2014. Vol. 50. No. 6. pp. 784-791.

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TY - JOUR

DO - 10.1134/S2070205114060161

UR - http://link.springer.com/10.1134/S2070205114060161

TI - The effect of self-organizing vinyl siloxane nanolayers on the corrosion behavior of aluminum in neutral chloride-containing solutions

T2 - Protection of Metals and Physical Chemistry of Surfaces

AU - Petrunin, M. A.

AU - Maksaeva, L B

AU - Yurasova, T A

AU - Terekhova, E V

AU - Maleeva, M A

AU - Shcherbina, A. A.

AU - Kotenev, V A

AU - Kablov, E. N.

AU - Tsivadze, A. Yu.

PY - 2014

DA - 2014/11/04

PB - Pleiades Publishing

SP - 784-791

IS - 6

VL - 50

SN - 2070-2051

SN - 2070-206X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2014_Petrunin,

author = {M. A. Petrunin and L B Maksaeva and T A Yurasova and E V Terekhova and M A Maleeva and A. A. Shcherbina and V A Kotenev and E. N. Kablov and A. Yu. Tsivadze},

title = {The effect of self-organizing vinyl siloxane nanolayers on the corrosion behavior of aluminum in neutral chloride-containing solutions},

journal = {Protection of Metals and Physical Chemistry of Surfaces},

year = {2014},

volume = {50},

publisher = {Pleiades Publishing},

month = {nov},

url = {http://link.springer.com/10.1134/S2070205114060161},

number = {6},

pages = {784--791},

doi = {10.1134/S2070205114060161}

}

MLA

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MLA Copy

Petrunin, M. A., et al. “The effect of self-organizing vinyl siloxane nanolayers on the corrosion behavior of aluminum in neutral chloride-containing solutions.” Protection of Metals and Physical Chemistry of Surfaces, vol. 50, no. 6, Nov. 2014, pp. 784-791. http://link.springer.com/10.1134/S2070205114060161.