Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix
Publication type: Journal Article
Publication date: 2015-07-01
scimago Q3
wos Q4
SJR: 0.211
CiteScore: 1.7
Impact factor: 0.8
ISSN: 20702051, 2070206X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Organic Chemistry
Abstract
A series of meso-tetra(benzo-12-crown-4)-substituted nickel(II), copper(II), zinc(II), palladium(II), and platinum(II) porphyrinates was synthesized. The structures of complexes were determined from the data of electronic absorption spectroscopy and MALDI TOF mass spectrometry. Analysis of the luminescence properties of metal porphyrinates in a polystyrene matrix at 25°C was performed. The quantum yields of fluorescence and phosphorescence were measured by an absolute method, and the lifetimes of fluorescence and phosphorescence were determined. On basis of the results obtained, analysis of the mechanisms of the influence of metal cations on the luminescence properties of the macrocyclic ligand in the molecules of 12-crown-4-substituted metal porphyrinates was performed.
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Chernyadev A. Yu. et al. Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix // Protection of Metals and Physical Chemistry of Surfaces. 2015. Vol. 51. No. 4. pp. 533-539.
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Chernyadev A. Yu., Tsivadze A. Y. Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix // Protection of Metals and Physical Chemistry of Surfaces. 2015. Vol. 51. No. 4. pp. 533-539.
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TY - JOUR
DO - 10.1134/S2070205115040073
UR - http://link.springer.com/10.1134/S2070205115040073
TI - Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix
T2 - Protection of Metals and Physical Chemistry of Surfaces
AU - Chernyadev, A Yu
AU - Tsivadze, A. Yu.
PY - 2015
DA - 2015/07/01
PB - Pleiades Publishing
SP - 533-539
IS - 4
VL - 51
SN - 2070-2051
SN - 2070-206X
ER -
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BibTex (up to 50 authors)
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@article{2015_Chernyadev,
author = {A Yu Chernyadev and A. Yu. Tsivadze},
title = {Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix},
journal = {Protection of Metals and Physical Chemistry of Surfaces},
year = {2015},
volume = {51},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S2070205115040073},
number = {4},
pages = {533--539},
doi = {10.1134/S2070205115040073}
}
Cite this
MLA
Copy
Chernyadev, A. Yu., et al. “Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix.” Protection of Metals and Physical Chemistry of Surfaces, vol. 51, no. 4, Jul. 2015, pp. 533-539. http://link.springer.com/10.1134/S2070205115040073.
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