Protection of Metals and Physical Chemistry of Surfaces

, том 51 , издание 6 , страницы 964-967

A new luminescent temperature sensor based on palladium(IV) porphyrinate in polystyrene matrix

Тип публикации: Journal Article

Дата публикации: 2015-11-03

Pleiades Publishing

Protection of Metals and Physical Chemistry of Surfaces

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SJR: 0.211

CiteScore: 1.7

Impact factor: 0.8

ISSN: 20702051, 2070206X

DOI: 10.1134/S2070205115060040

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

Organic Chemistry

Краткое описание

A composite material based on 15-crown-5-substituted palladium(IV) porphyrinate (PdCl2TCP) and polystyrene is obtained that changes its luminescent properties in the red spectral region at transition from the liquid nitrogen temperature (77 K) to 358 K. Variation of fluorescence and phosphorescence spectra of the material in the course of its heating is analyzed. It is shown that one can determine the sample temperature on the basis of the ratio of intensity of fluorescence and phosphorescence transitions for palladium(IV) porphyrinate in polystyrene. Such a material is a promising luminescent temperature sensor with a very wide range of registered temperatures and a possibility of temperature control in microand even nanosize sample regions due to the fact that temperature determination is based on physical processes occurring in every individual PdCl2TCP molecule.

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Protection of Metals and Physical Chemistry of Surfaces	Protection of Metals and Physical Chemistry of Surfaces, 12, 75% Protection of Metals and Physical Chemistry of Surfaces 12 публикаций, 75%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 2, 12.5% International Journal of Molecular Sciences 2 публикации, 12.5%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 6.25% Russian Journal of Inorganic Chemistry 1 публикация, 6.25%
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Chernyadev A. Yu. et al. A new luminescent temperature sensor based on palladium(IV) porphyrinate in polystyrene matrix // Protection of Metals and Physical Chemistry of Surfaces. 2015. Vol. 51. No. 6. pp. 964-967.

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Chernyadev A. Yu., Kotenev V. A., Tsivadze A. Y. A new luminescent temperature sensor based on palladium(IV) porphyrinate in polystyrene matrix // Protection of Metals and Physical Chemistry of Surfaces. 2015. Vol. 51. No. 6. pp. 964-967.

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TY - JOUR

DO - 10.1134/S2070205115060040

UR - http://link.springer.com/10.1134/S2070205115060040

TI - A new luminescent temperature sensor based on palladium(IV) porphyrinate in polystyrene matrix

T2 - Protection of Metals and Physical Chemistry of Surfaces

AU - Chernyadev, A Yu

AU - Kotenev, V A

AU - Tsivadze, A. Yu.

PY - 2015

DA - 2015/11/03

PB - Pleiades Publishing

SP - 964-967

IS - 6

VL - 51

SN - 2070-2051

SN - 2070-206X

ER -

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@article{2015_Chernyadev,

author = {A Yu Chernyadev and V A Kotenev and A. Yu. Tsivadze},

title = {A new luminescent temperature sensor based on palladium(IV) porphyrinate in polystyrene matrix},

journal = {Protection of Metals and Physical Chemistry of Surfaces},

year = {2015},

volume = {51},

publisher = {Pleiades Publishing},

month = {nov},

url = {http://link.springer.com/10.1134/S2070205115060040},

number = {6},

pages = {964--967},

doi = {10.1134/S2070205115060040}

}

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Chernyadev, A. Yu., et al. “A new luminescent temperature sensor based on palladium(IV) porphyrinate in polystyrene matrix.” Protection of Metals and Physical Chemistry of Surfaces, vol. 51, no. 6, Nov. 2015, pp. 964-967. http://link.springer.com/10.1134/S2070205115060040.