volume 54 issue 5 pages 795-803

The Effect of Vinyl-Siloxane Nanolayers on the Corrosion Behavior of Zinc

M. A. Petrunin 1
L B Maksaeva 1
N A Gladkikh 1
E N Narkevich 1
T A Yurasova 1
A A Rybkin 1
E V Terekhova 1
V A Kotenev 1
E. N. Kablov 1
Publication typeJournal Article
Publication date2018-09-01
scimago Q3
wos Q4
SJR0.211
CiteScore1.7
Impact factor0.8
ISSN20702051, 2070206X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Organic Chemistry
Abstract
The effect of surface siloxane nanolayers on the electrochemical and corrosion behavior of zinc is studied. It is found that surface self-organizing siloxane nanolayers inhibit anodic dissolution of zinc and its corrosion in chloride-containing electrolytes and under atmospheric conditions and can also cause a decrease in the pitting rate on the metal surface. It is established that the inhibiting effect of the vinyl-siloxane nanolayer depends on its thickness. Thus, the surface siloxane monolayer is insufficient for suppressing corrosion processes. Siloxane layers with a thickness above two or three molecular layers most efficiently inhibit corrosion and local dissolution of zinc. At this thickness, the most ordered surface structures are apparently formed. The FTIR method is used to show that the formed surface self-organizing vinyl-siloxane nanolayers on zinc are stable under exposure to sodium chloride solution and preserve strong bonds with the metal surface despite the occurring corrosion processes.
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Petrunin M. A. et al. The Effect of Vinyl-Siloxane Nanolayers on the Corrosion Behavior of Zinc // Protection of Metals and Physical Chemistry of Surfaces. 2018. Vol. 54. No. 5. pp. 795-803.
GOST all authors (up to 50) Copy
Petrunin M. A., Maksaeva L. B., Gladkikh N. A., Narkevich E. N., Yurasova T. A., Rybkin A. A., Terekhova E. V., Kotenev V. A., Kablov E. N., Tsivadze A. Y. The Effect of Vinyl-Siloxane Nanolayers on the Corrosion Behavior of Zinc // Protection of Metals and Physical Chemistry of Surfaces. 2018. Vol. 54. No. 5. pp. 795-803.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S2070205118040123
UR - http://link.springer.com/10.1134/S2070205118040123
TI - The Effect of Vinyl-Siloxane Nanolayers on the Corrosion Behavior of Zinc
T2 - Protection of Metals and Physical Chemistry of Surfaces
AU - Petrunin, M. A.
AU - Maksaeva, L B
AU - Gladkikh, N A
AU - Narkevich, E N
AU - Yurasova, T A
AU - Rybkin, A A
AU - Terekhova, E V
AU - Kotenev, V A
AU - Kablov, E. N.
AU - Tsivadze, A. Yu.
PY - 2018
DA - 2018/09/01
PB - Pleiades Publishing
SP - 795-803
IS - 5
VL - 54
SN - 2070-2051
SN - 2070-206X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Petrunin,
author = {M. A. Petrunin and L B Maksaeva and N A Gladkikh and E N Narkevich and T A Yurasova and A A Rybkin and E V Terekhova and V A Kotenev and E. N. Kablov and A. Yu. Tsivadze},
title = {The Effect of Vinyl-Siloxane Nanolayers on the Corrosion Behavior of Zinc},
journal = {Protection of Metals and Physical Chemistry of Surfaces},
year = {2018},
volume = {54},
publisher = {Pleiades Publishing},
month = {sep},
url = {http://link.springer.com/10.1134/S2070205118040123},
number = {5},
pages = {795--803},
doi = {10.1134/S2070205118040123}
}
MLA
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MLA Copy
Petrunin, M. A., et al. “The Effect of Vinyl-Siloxane Nanolayers on the Corrosion Behavior of Zinc.” Protection of Metals and Physical Chemistry of Surfaces, vol. 54, no. 5, Sep. 2018, pp. 795-803. http://link.springer.com/10.1134/S2070205118040123.