About the Nature of Excessive Gas Evolution in the Case of Electrochemical Hydrogenation of Palladium in an Alkaline Solution
Publication type: Journal Article
Publication date: 2019-01-01
scimago Q3
wos Q4
SJR: 0.211
CiteScore: 1.7
Impact factor: 0.8
ISSN: 20702051, 2070206X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Organic Chemistry
Abstract
The gas evolution process on fully hydrogenated Pd (H : Pd = 0.73) cathodes is studied in a 1 M solution of NaOH at ambient temperature. A phenomenon of spontaneous gas evolution on the surface of PdH after electrolysis and transfer of the sample into a burette with a 1 M solution of NaOH or distilled water is discovered. The volume of the gas that spontaneously evolved on the surface of PdH is 0.22–0.24 cm3/cm2 in a 1 M solution of NaOH and 0.40–0.43 cm3/cm2 in distilled water. It is proposed that the spontaneously evolving gas is not hydrogen from PdH, but results from the cavitation process.
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Lyakhov B. F. et al. About the Nature of Excessive Gas Evolution in the Case of Electrochemical Hydrogenation of Palladium in an Alkaline Solution // Protection of Metals and Physical Chemistry of Surfaces. 2019. Vol. 55. No. 1. pp. 203-206.
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Lyakhov B. F., Solodkova L. N., Vashchenko S. V., Bardyshev I., Kotenev V. A., Tsivadze A. Y. About the Nature of Excessive Gas Evolution in the Case of Electrochemical Hydrogenation of Palladium in an Alkaline Solution // Protection of Metals and Physical Chemistry of Surfaces. 2019. Vol. 55. No. 1. pp. 203-206.
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RIS
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TY - JOUR
DO - 10.1134/S2070205119020199
UR - http://link.springer.com/10.1134/S2070205119020199
TI - About the Nature of Excessive Gas Evolution in the Case of Electrochemical Hydrogenation of Palladium in an Alkaline Solution
T2 - Protection of Metals and Physical Chemistry of Surfaces
AU - Lyakhov, B. F.
AU - Solodkova, L N
AU - Vashchenko, S V
AU - Bardyshev, I.I
AU - Kotenev, V A
AU - Tsivadze, A. Yu.
PY - 2019
DA - 2019/01/01
PB - Pleiades Publishing
SP - 203-206
IS - 1
VL - 55
SN - 2070-2051
SN - 2070-206X
ER -
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@article{2019_Lyakhov,
author = {B. F. Lyakhov and L N Solodkova and S V Vashchenko and I.I Bardyshev and V A Kotenev and A. Yu. Tsivadze},
title = {About the Nature of Excessive Gas Evolution in the Case of Electrochemical Hydrogenation of Palladium in an Alkaline Solution},
journal = {Protection of Metals and Physical Chemistry of Surfaces},
year = {2019},
volume = {55},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S2070205119020199},
number = {1},
pages = {203--206},
doi = {10.1134/S2070205119020199}
}
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Lyakhov, B. F., et al. “About the Nature of Excessive Gas Evolution in the Case of Electrochemical Hydrogenation of Palladium in an Alkaline Solution.” Protection of Metals and Physical Chemistry of Surfaces, vol. 55, no. 1, Jan. 2019, pp. 203-206. http://link.springer.com/10.1134/S2070205119020199.
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