The Formation of Self-Organizing Organosilicone Layers on a Carbon Steel Surface and Their Effect on the Electrochemical and Corrosion Behavior of the Metal
M. A. Petrunin
1
,
N A Gladkikh
1
,
M A Maleeva
1
,
L B Maksaeva
1
,
Yu V Kostina
2
,
A V Shapagin
1
,
T A Yurasova
1
,
V A Kotenev
1
,
Publication type: Journal Article
Publication date: 2019-09-01
scimago Q3
wos Q4
SJR: 0.211
CiteScore: 1.7
Impact factor: 0.8
ISSN: 20702051, 2070206X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Organic Chemistry
Abstract
Adsorption on the carbon steel surface of vinyl trimethoxysilane and γ-aminopropyl triethoxysilane from aqueous solution is studied using the methods of Fourier-transform infrared spectroscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy. A mechanism of surface layer formation is suggested. It is shown that in the course of adsorption silanes interact with hydroxyl groups of the metal surface with formation of Fe–O–Si bonds. The effect of organosilicone layers on the electrochemical behavior of steel is studied. It is found that the potential of pitting formation of steel is shifted in the presence of organosilicone layers into the range of positive values, which points to inhibition of local anodic dissolution of the metal. Accelerated corrosion tests of steel samples in a climatic chamber are performed, and the corrosion-inhibiting effect of vinyl- and amino-containing surface layers is shown.
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Petrunin M. A. et al. The Formation of Self-Organizing Organosilicone Layers on a Carbon Steel Surface and Their Effect on the Electrochemical and Corrosion Behavior of the Metal // Protection of Metals and Physical Chemistry of Surfaces. 2019. Vol. 55. No. 5. pp. 895-902.
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Petrunin M. A., Gladkikh N. A., Maleeva M. A., Maksaeva L. B., Kostina Yu. V., Shapagin A. V., Yurasova T. A., Kotenev V. A., Tsivadze A. Y. The Formation of Self-Organizing Organosilicone Layers on a Carbon Steel Surface and Their Effect on the Electrochemical and Corrosion Behavior of the Metal // Protection of Metals and Physical Chemistry of Surfaces. 2019. Vol. 55. No. 5. pp. 895-902.
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TY - JOUR
DO - 10.1134/S2070205119050204
UR - http://link.springer.com/10.1134/S2070205119050204
TI - The Formation of Self-Organizing Organosilicone Layers on a Carbon Steel Surface and Their Effect on the Electrochemical and Corrosion Behavior of the Metal
T2 - Protection of Metals and Physical Chemistry of Surfaces
AU - Petrunin, M. A.
AU - Gladkikh, N A
AU - Maleeva, M A
AU - Maksaeva, L B
AU - Kostina, Yu V
AU - Shapagin, A V
AU - Yurasova, T A
AU - Kotenev, V A
AU - Tsivadze, A. Yu.
PY - 2019
DA - 2019/09/01
PB - Pleiades Publishing
SP - 895-902
IS - 5
VL - 55
SN - 2070-2051
SN - 2070-206X
ER -
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BibTex (up to 50 authors)
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@article{2019_Petrunin,
author = {M. A. Petrunin and N A Gladkikh and M A Maleeva and L B Maksaeva and Yu V Kostina and A V Shapagin and T A Yurasova and V A Kotenev and A. Yu. Tsivadze},
title = {The Formation of Self-Organizing Organosilicone Layers on a Carbon Steel Surface and Their Effect on the Electrochemical and Corrosion Behavior of the Metal},
journal = {Protection of Metals and Physical Chemistry of Surfaces},
year = {2019},
volume = {55},
publisher = {Pleiades Publishing},
month = {sep},
url = {http://link.springer.com/10.1134/S2070205119050204},
number = {5},
pages = {895--902},
doi = {10.1134/S2070205119050204}
}
Cite this
MLA
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Petrunin, M. A., et al. “The Formation of Self-Organizing Organosilicone Layers on a Carbon Steel Surface and Their Effect on the Electrochemical and Corrosion Behavior of the Metal.” Protection of Metals and Physical Chemistry of Surfaces, vol. 55, no. 5, Sep. 2019, pp. 895-902. http://link.springer.com/10.1134/S2070205119050204.
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