,
volume 37
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issue 1
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pages 12-25
Transition metal complexes with “non-innocent” ligands in the activation of hydrogen sulfide
Publication type: Journal Article
Publication date: 2011-01-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of hydrogen sulfide with transition metal complexes containing redox-active ligands are studied. A combination of electrochemical and spectral data indicates that the one-electron process affording the hydrogen sulfide radical and monoanionic complexes is an elementary act for the most part of the reactions studied. The accessibility of the metal center in the Co, Ni, Zn, and Pt complexes allows hydrogen sulfide to preliminary coordinate to the metal followed by the inner-sphere electron transfer in the hydrogen sulfide-metal-organic ligand system. Active intermediates (radical cation, thiyl radical, and proton) formed due to oxidation react with aromatic substrates. The substitution reaction in the aromatic ring produces a mixture of isomeric thiols and dimerization products of organylthiyl radicals (disulfides).
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14
Total citations:
14
Citations from 2024:
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(7.14%)
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GOST
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Smolyaninov I. V. et al. Transition metal complexes with “non-innocent” ligands in the activation of hydrogen sulfide // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. Vol. 37. No. 1. pp. 12-25.
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Smolyaninov I. V., Okhlobystin A. O., Poddelsky A. I., Berberova N. T., Eremenko I. L. Transition metal complexes with “non-innocent” ligands in the activation of hydrogen sulfide // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. Vol. 37. No. 1. pp. 12-25.
Cite this
RIS
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TY - JOUR
DO - 10.1134/s107032841012105x
UR - https://doi.org/10.1134/s107032841012105x
TI - Transition metal complexes with “non-innocent” ligands in the activation of hydrogen sulfide
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Smolyaninov, I V
AU - Okhlobystin, A O
AU - Poddelsky, A I
AU - Berberova, N T
AU - Eremenko, I. L.
PY - 2011
DA - 2011/01/01
PB - Pleiades Publishing
SP - 12-25
IS - 1
VL - 37
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Smolyaninov,
author = {I V Smolyaninov and A O Okhlobystin and A I Poddelsky and N T Berberova and I. L. Eremenko},
title = {Transition metal complexes with “non-innocent” ligands in the activation of hydrogen sulfide},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2011},
volume = {37},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134/s107032841012105x},
number = {1},
pages = {12--25},
doi = {10.1134/s107032841012105x}
}
Cite this
MLA
Copy
Smolyaninov, I. V., et al. “Transition metal complexes with “non-innocent” ligands in the activation of hydrogen sulfide.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 37, no. 1, Jan. 2011, pp. 12-25. https://doi.org/10.1134/s107032841012105x.
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