Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 2, pages 127-143
Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples
M. A. Shmelev
1
,
G. N. Kuznetsova
1
,
F.M. Dolgushin
1, 2
,
Yu K Voronina
1
,
N. V. Gogoleva
1
,
M. A. Kiskin
1
,
V.K. Ivanov
1
,
A. A. Sidorov
1
,
I. L. Eremenko
1, 2
Publication type: Journal Article
Publication date: 2021-02-24
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A series of the cadmium and zinc carboxylate complexes with anions of pentafluorobenzoic (HРfbz) and 2,3,4,5-tetrafluorobenzoic (HТfbz) acids and N-donor ligands (1,10-phenanthroline (Phen) and quinoline (Quin)), [Cd(Pfbz)2(Phen)]n (I), [Cd(Рfbz)2(Рhen)2]·2MeCN (II), [Zn(H2O)-(Рfbz)2(Рhen)] (III), [Zn2Cd(Рfbz)6(Рhen)2]⋅2C6H6 (IV), [Cd2(H2O)2(Tfbz)4(Рhen)2] (V), [Cd2-(H2O)2(Tfbz)4(Quin)2] (VI), and [Cd(Tfbz)2(Phen)2]⋅HTfbz (VII), is synthesized. The structures of new complexes I–VII are determined by X-ray diffraction analysis (CIF files CCDC nos. 1871300, 2005461, 2005462, 2005464, 2005466, 2005465, and 2005459, respectively). The majority of the synthesized compounds is typical of intramolecular stacking interactions between the coordinated molecules of the aromatic N-donor ligands and fluorinated substituents of the carboxylate anions. These interactions lead to the formation of unusual compounds, which are different in the cases of pentafluorobenzoates and tetrafluorobenzoates, in particular, coordination polymer I and binuclear complexes V and VI with coordinated water molecules. The synthesized zinc and cadmium compounds differ in structure and composition.
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- We do not take into account publications without a DOI.
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Shmelev M. A. et al. Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 2. pp. 127-143.
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Shmelev M. A., Kuznetsova G. N., Dolgushin F., Voronina Yu. K., Gogoleva N. V., Kiskin M. A., Ivanov V., Sidorov A. A., Eremenko I. L. Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 2. pp. 127-143.
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TY - JOUR
DO - 10.1134/S1070328421020068
UR - https://doi.org/10.1134/S1070328421020068
TI - Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shmelev, M. A.
AU - Kuznetsova, G. N.
AU - Voronina, Yu K
AU - Gogoleva, N. V.
AU - Kiskin, M. A.
AU - Ivanov, V.K.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
AU - Dolgushin, F.M.
PY - 2021
DA - 2021/02/24 00:00:00
PB - Pleiades Publishing
SP - 127-143
IS - 2
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Shmelev,
author = {M. A. Shmelev and G. N. Kuznetsova and Yu K Voronina and N. V. Gogoleva and M. A. Kiskin and V.K. Ivanov and A. A. Sidorov and I. L. Eremenko and F.M. Dolgushin},
title = {Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S1070328421020068},
number = {2},
pages = {127--143},
doi = {10.1134/S1070328421020068}
}
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Shmelev, M. A., et al. “Influence of the Fluorinated Aromatic Fragments on the Structures of the Cadmium and Zinc Carboxylate Complexes Using Pentafluorobenzoates and 2,3,4,5-Tetrafluorobenzoates as Examples.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 2, Feb. 2021, pp. 127-143. https://doi.org/10.1134/S1070328421020068.