A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves

Publication typeJournal Article
Publication date2021-04-14
scimago Q4
wos Q4
SJR0.189
CiteScore1.7
Impact factor1.1
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A new metal-organic framework {Zn4(BDC)3(OAc)2(DMF)4} (BDC = terephthalate anion) was synthesized under solvothermal conditions in a 3D-printed polypropylene autoclave. The product was isolated in a pure state and characterized by elemental analysis and X-ray diffraction (CIF file CCDC no. 2025811). The formation of this product, instead of the expected {Zn4O(BDC)3} (MOF-5), was probably due to a change in the conditions of solvothermal synthesis caused by disruption of the integrity of the polypropylene autoclave. This is a drawback of this method of screening of metal-organic frameworks, which, however, in some cases givs rise to new representatives of this class of crystalline materials.
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GOST Copy
Denisov G. L. et al. A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 4. pp. 253-260.
GOST all authors (up to 50) Copy
Denisov G. L., Primakov P. V., Nelyubina Yu. V. A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 4. pp. 253-260.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/s1070328421040011
UR - https://doi.org/10.1134/s1070328421040011
TI - A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Denisov, G L
AU - Primakov, P V
AU - Nelyubina, Yu V
PY - 2021
DA - 2021/04/14
PB - Pleiades Publishing
SP - 253-260
IS - 4
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Denisov,
author = {G L Denisov and P V Primakov and Yu V Nelyubina},
title = {A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/s1070328421040011},
number = {4},
pages = {253--260},
doi = {10.1134/s1070328421040011}
}
MLA
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MLA Copy
Denisov, G. L., et al. “A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 4, Apr. 2021, pp. 253-260. https://doi.org/10.1134/s1070328421040011.