Russian Journal of General Chemistry, volume 92, issue 8, pages 1443-1448

Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone

Publication type: Journal Article
Publication date: 2022-08-01
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Impact factor: 0.9
ISSN: 10703632, 16083350
General Chemistry
Abstract
Low-temperature (–90°C) ozonolysis of tris(trimethylsilyl)silane gave tris(trimethylsilyl)silanol and 1,1,1-trimethyl-2,2-bis(trimethylsiloxy)disilan-2-ol. The primary isotope effect in the reaction of tris(trimethylsilyl)silane with ozone at –90°C is equal to 5.5 and is consistent with the theoretical value calculated at the B3LYP/6-31+G(2d,p) level of theory assuming abstraction of H(D) from the Si–H(D) bond by ozone. Possible reaction mechanisms, namely radical, ionic, and ozone insertion into the Si–H bond, are discussed.
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Grabovskii S. A. Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone // Russian Journal of General Chemistry. 2022. Vol. 92. No. 8. pp. 1443-1448.
GOST all authors (up to 50) Copy
Grabovskii S. A. Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone // Russian Journal of General Chemistry. 2022. Vol. 92. No. 8. pp. 1443-1448.
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TY - JOUR
DO - 10.1134/s1070363222080114
UR - https://doi.org/10.1134/s1070363222080114
TI - Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone
T2 - Russian Journal of General Chemistry
AU - Grabovskii, Stanislav A.
PY - 2022
DA - 2022/08/01
PB - Pleiades Publishing
SP - 1443-1448
IS - 8
VL - 92
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2022_Grabovskii,
author = {Stanislav A. Grabovskii},
title = {Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone},
journal = {Russian Journal of General Chemistry},
year = {2022},
volume = {92},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/s1070363222080114},
number = {8},
pages = {1443--1448},
doi = {10.1134/s1070363222080114}
}
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Grabovskii, Stanislav A.. “Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone.” Russian Journal of General Chemistry, vol. 92, no. 8, Aug. 2022, pp. 1443-1448. https://doi.org/10.1134/s1070363222080114.
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