Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3
Publication type: Journal Article
Publication date: 2008-04-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
The result of acylation of dibenzoaza-14-crowns-4 containing a 4-oxopiperidine fragment with acetic anhydride depends on the substituent on the nitrogen atom. The NH-substrates initially undergo acylation at the piperidine nitrogen atom, followed by enolization and O-acylation. The acylation of N-methyl derivatives is accompanied by cleavage of the piperidine ring at the C-N bond with formation of acetylamino-substituted dibenzo-16-crowns-3. The structure of the latter was determined by X-ray analysis.
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Levov A. N. et al. Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3 // Russian Journal of Organic Chemistry. 2008. Vol. 44. No. 4. pp. 612-616.
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Levov A. N., Le Tuan A., Soldatenkov A. T., Khieu C. K., Khrustalev V. N. Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3 // Russian Journal of Organic Chemistry. 2008. Vol. 44. No. 4. pp. 612-616.
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TY - JOUR
DO - 10.1134/s1070428008040246
UR - https://doi.org/10.1134/s1070428008040246
TI - Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3
T2 - Russian Journal of Organic Chemistry
AU - Levov, A N
AU - Le Tuan, An
AU - Soldatenkov, A T
AU - Khieu, Chyong Khong
AU - Khrustalev, V. N.
PY - 2008
DA - 2008/04/01
PB - Pleiades Publishing
SP - 612-616
IS - 4
VL - 44
SN - 1070-4280
SN - 1608-3393
ER -
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@article{2008_Levov,
author = {A N Levov and An Le Tuan and A T Soldatenkov and Chyong Khong Khieu and V. N. Khrustalev},
title = {Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3},
journal = {Russian Journal of Organic Chemistry},
year = {2008},
volume = {44},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/s1070428008040246},
number = {4},
pages = {612--616},
doi = {10.1134/s1070428008040246}
}
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MLA
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Levov, A. N., et al. “Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3.” Russian Journal of Organic Chemistry, vol. 44, no. 4, Apr. 2008, pp. 612-616. https://doi.org/10.1134/s1070428008040246.