Synthesis and Thermal and Rheological Properties of Polydimethylsiloxanes Modified with Benzoic Acid Fragments
V V Gorodov
1
,
P A Tikhonov
1
,
M I Buzin
2, 3
,
V G Vasilev
2
,
S A Milenin
1
,
D I Shragin
1, 2
,
V.S. Papkov
2
,
A M Muzafarov
1, 2
Publication type: Journal Article
Publication date: 2018-05-01
scimago Q3
wos Q4
SJR: 0.234
CiteScore: 1.8
Impact factor: 1.0
ISSN: 15600904, 15556123
Materials Chemistry
Ceramics and Composites
Polymers and Plastics
Abstract
4-(Dimethylvinylsilyl)benzoic acid is obtained by organolithium synthesis. Polydimethylsiloxanes containing silicon hydride groups are modified by introducing benzoic acid fragments via the hydrosilylation reaction. The thermal and rheological properties of the copolymers formed are studied. It is found that a rise in the content of benzoic acid results in a shift in the glass-transition temperature to a higher temperature region and the copolymers do not crystallize. Benzoic acid fragments improve the intermolecular interaction of polydimethylsiloxane chains more strongly than the ones of undecenoic acid.
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GOST
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Gorodov V. V. et al. Synthesis and Thermal and Rheological Properties of Polydimethylsiloxanes Modified with Benzoic Acid Fragments // Polymer Science - Series B. 2018. Vol. 60. No. 3. pp. 290-298.
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Gorodov V. V., Tikhonov P. A., Buzin M. I., Vasilev V. G., Milenin S. A., Shragin D. I., Papkov V., Muzafarov A. M. Synthesis and Thermal and Rheological Properties of Polydimethylsiloxanes Modified with Benzoic Acid Fragments // Polymer Science - Series B. 2018. Vol. 60. No. 3. pp. 290-298.
Cite this
RIS
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TY - JOUR
DO - 10.1134/s1560090418030041
UR - https://doi.org/10.1134/s1560090418030041
TI - Synthesis and Thermal and Rheological Properties of Polydimethylsiloxanes Modified with Benzoic Acid Fragments
T2 - Polymer Science - Series B
AU - Gorodov, V V
AU - Tikhonov, P A
AU - Buzin, M I
AU - Vasilev, V G
AU - Milenin, S A
AU - Shragin, D I
AU - Papkov, V.S.
AU - Muzafarov, A M
PY - 2018
DA - 2018/05/01
PB - Pleiades Publishing
SP - 290-298
IS - 3
VL - 60
SN - 1560-0904
SN - 1555-6123
ER -
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BibTex (up to 50 authors)
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@article{2018_Gorodov,
author = {V V Gorodov and P A Tikhonov and M I Buzin and V G Vasilev and S A Milenin and D I Shragin and V.S. Papkov and A M Muzafarov},
title = {Synthesis and Thermal and Rheological Properties of Polydimethylsiloxanes Modified with Benzoic Acid Fragments},
journal = {Polymer Science - Series B},
year = {2018},
volume = {60},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/s1560090418030041},
number = {3},
pages = {290--298},
doi = {10.1134/s1560090418030041}
}
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MLA
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Gorodov, V. V., et al. “Synthesis and Thermal and Rheological Properties of Polydimethylsiloxanes Modified with Benzoic Acid Fragments.” Polymer Science - Series B, vol. 60, no. 3, May. 2018, pp. 290-298. https://doi.org/10.1134/s1560090418030041.
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