Synthesis and properties of poly[2-(4′-oxyphenylene)-5-benzimidazole] and a proton-exchange membrane produced on its basis
1
Engineering Center of Hydrogen Technologies and Alternative Energetics, New Energy Projects National Innovation Company, Moscow, Russia
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Publication type: Journal Article
Publication date: 2009-09-11
scimago Q3
wos Q4
SJR: 0.322
CiteScore: 2.6
Impact factor: 1.1
ISSN: 18112382, 1555614X
Materials Chemistry
General Chemistry
Polymers and Plastics
Abstract
A monomer of the A-B type, 3,4-diamino-4′-carboxydiphenyloxide, has been synthesized via a series of consecutive transformations of 5-chloro-2-nitroaniline. The homopolycondensation of the monomer in Eaton’s reagent at 140°C yields poly[2-(4′-oxyphenylene)-5-benzimidazole] soluble in organic solvents. A membrane containing 51% H3PO4 (2.9 acid molecules pert monomer unit) and possessing a proton conductivity of 0.025 S/cm at 160°C is produced by doping a polymer film with 60% H3PO4.
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Leikin A. Yu. et al. Synthesis and properties of poly[2-(4′-oxyphenylene)-5-benzimidazole] and a proton-exchange membrane produced on its basis // Polymer Science - Series C. 2009. Vol. 51. No. 1. pp. 12-16.
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Leikin A. Yu., Rusanov A. L., Begunov R. S., Fomenkov A. I. Synthesis and properties of poly[2-(4′-oxyphenylene)-5-benzimidazole] and a proton-exchange membrane produced on its basis // Polymer Science - Series C. 2009. Vol. 51. No. 1. pp. 12-16.
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RIS
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TY - JOUR
DO - 10.1134/s1811238209010044
UR - https://doi.org/10.1134/s1811238209010044
TI - Synthesis and properties of poly[2-(4′-oxyphenylene)-5-benzimidazole] and a proton-exchange membrane produced on its basis
T2 - Polymer Science - Series C
AU - Leikin, A Yu
AU - Rusanov, A. L.
AU - Begunov, R S
AU - Fomenkov, A I
PY - 2009
DA - 2009/09/11
PB - Pleiades Publishing
SP - 12-16
IS - 1
VL - 51
SN - 1811-2382
SN - 1555-614X
ER -
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BibTex (up to 50 authors)
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@article{2009_Leikin,
author = {A Yu Leikin and A. L. Rusanov and R S Begunov and A I Fomenkov},
title = {Synthesis and properties of poly[2-(4′-oxyphenylene)-5-benzimidazole] and a proton-exchange membrane produced on its basis},
journal = {Polymer Science - Series C},
year = {2009},
volume = {51},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/s1811238209010044},
number = {1},
pages = {12--16},
doi = {10.1134/s1811238209010044}
}
Cite this
MLA
Copy
Leikin, A. Yu., et al. “Synthesis and properties of poly[2-(4′-oxyphenylene)-5-benzimidazole] and a proton-exchange membrane produced on its basis.” Polymer Science - Series C, vol. 51, no. 1, Sep. 2009, pp. 12-16. https://doi.org/10.1134/s1811238209010044.