volume 46 issue 6 pages 1474-1485

Cycloheptatriene dimers: New precursors of diamantane

František Tureček
Vladimír Hanuš
PETR SEDMERA
Helena Antropiusová
Karel Mach
Publication typeJournal Article
Publication date2011-08-12
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CiteScore
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ISSN00100765, 12126950
General Chemistry
Abstract

Dimerization of cycloheptatriene, catalyzed by titanium complexes, afforded pentacyclo[8.4.0.03,7.04,14.06,11]tetradeca-8,12-diene (I) (10%) and pentacyclo[7.5.0.02,8.05,14.07,11]tetradeca-3,12-diene (II) (90%). Structure of both dimers and their derivatives was determined by means of 1H NMR, 13C NMR and mass spectra. On heating, the diene II was converted into the more stable isomer I. On hydrogenation and further catalytic isomerization, both I and II gave diamantane in high yield.

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GOST Copy
Tureček F. et al. Cycloheptatriene dimers: New precursors of diamantane // Collection of Czechoslovak Chemical Communications. 2011. Vol. 46. No. 6. pp. 1474-1485.
GOST all authors (up to 50) Copy
Tureček F., Hanuš V., SEDMERA P., Antropiusová H., Mach K. Cycloheptatriene dimers: New precursors of diamantane // Collection of Czechoslovak Chemical Communications. 2011. Vol. 46. No. 6. pp. 1474-1485.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1135/cccc19811474
UR - https://doi.org/10.1135/cccc19811474
TI - Cycloheptatriene dimers: New precursors of diamantane
T2 - Collection of Czechoslovak Chemical Communications
AU - Tureček, František
AU - Hanuš, Vladimír
AU - SEDMERA, PETR
AU - Antropiusová, Helena
AU - Mach, Karel
PY - 2011
DA - 2011/08/12
PB - Institute of Organic Chemistry & Biochemistry
SP - 1474-1485
IS - 6
VL - 46
SN - 0010-0765
SN - 1212-6950
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Tureček,
author = {František Tureček and Vladimír Hanuš and PETR SEDMERA and Helena Antropiusová and Karel Mach},
title = {Cycloheptatriene dimers: New precursors of diamantane},
journal = {Collection of Czechoslovak Chemical Communications},
year = {2011},
volume = {46},
publisher = {Institute of Organic Chemistry & Biochemistry},
month = {aug},
url = {https://doi.org/10.1135/cccc19811474},
number = {6},
pages = {1474--1485},
doi = {10.1135/cccc19811474}
}
MLA
Cite this
MLA Copy
Tureček, František, et al. “Cycloheptatriene dimers: New precursors of diamantane.” Collection of Czechoslovak Chemical Communications, vol. 46, no. 6, Aug. 2011, pp. 1474-1485. https://doi.org/10.1135/cccc19811474.