Complexes of platinum group metals with the ambidentate ligands Ph2P(CF2)nSPh (n = 1, 2)
Publication type: Journal Article
Publication date: 1983-09-01
scimago Q3
wos Q4
SJR: 0.254
CiteScore: 2.0
Impact factor: 1.0
ISSN: 00084042, 14803291
DOI:
10.1139/v83-386
General Chemistry
Catalysis
Organic Chemistry
Abstract
The potentially bidentate ligands Ph2P(CH2)nSPh (n = 1, 2) form complexes of rhodium(I), iridium(I), palladium(II), or platinum(II) in which ligands are coordinated to a metal centre either by the phosphine function alone, or by the phosphine and thioether functions, or both. Successive displacement of chloro-ligands from [MCl2(Ph2PCH2CH2SPh)2] (M = Pd, Pt) gives the cationic complexes (MCl(Ph2PCH2CH2SPh)2]+ and [M(Ph2PCH2CH2SPh)2]2+. In the latter each ligand is chelating, but in the former, one ligand is monodentate and the other bidentate. Homopolynuclear complexes may also be synthesized in which metal centres are bridged by Ph2P(CH2)nSPh. The complex [RhCl(Ph2PCH2SPh)(C8H12)] contains cyclooctadiene as a monodentate ligand.
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GOST
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Sanger A. R. Complexes of platinum group metals with the ambidentate ligands Ph2P(CF2)nSPh (n = 1, 2) // Canadian Journal of Chemistry. 1983. Vol. 61. No. 9. pp. 2214-2219.
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Sanger A. R. Complexes of platinum group metals with the ambidentate ligands Ph2P(CF2)nSPh (n = 1, 2) // Canadian Journal of Chemistry. 1983. Vol. 61. No. 9. pp. 2214-2219.
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RIS
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TY - JOUR
DO - 10.1139/v83-386
UR - https://doi.org/10.1139/v83-386
TI - Complexes of platinum group metals with the ambidentate ligands Ph2P(CF2)nSPh (n = 1, 2)
T2 - Canadian Journal of Chemistry
AU - Sanger, Alan R
PY - 1983
DA - 1983/09/01
PB - Canadian Science Publishing
SP - 2214-2219
IS - 9
VL - 61
SN - 0008-4042
SN - 1480-3291
ER -
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BibTex (up to 50 authors)
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@article{1983_Sanger,
author = {Alan R Sanger},
title = {Complexes of platinum group metals with the ambidentate ligands Ph2P(CF2)nSPh (n = 1, 2)},
journal = {Canadian Journal of Chemistry},
year = {1983},
volume = {61},
publisher = {Canadian Science Publishing},
month = {sep},
url = {https://doi.org/10.1139/v83-386},
number = {9},
pages = {2214--2219},
doi = {10.1139/v83-386}
}
Cite this
MLA
Copy
Sanger, Alan R.. “Complexes of platinum group metals with the ambidentate ligands Ph2P(CF2)nSPh (n = 1, 2).” Canadian Journal of Chemistry, vol. 61, no. 9, Sep. 1983, pp. 2214-2219. https://doi.org/10.1139/v83-386.