volume 13 issue 1 pages 92-98

Solvent-induced supramolecular assemblies of crown-substituted ruthenium phthalocyaninate:

Publication typeJournal Article
Publication date2009-01-01
scimago Q3
wos Q4
SJR0.228
CiteScore1.8
Impact factor0.9
ISSN10884246, 10991409
General Chemistry
Abstract

The information concerning the architecture of supramolecular assemblies, which are composed of ruthenium(II) tetra-15-crown-5-phthalocyaninate with axially coordinated triethylenediamine molecules, has been obtained with the application of atomic force microscopy. The ensembles are formed in Ru ( II ) complex solutions in chloroform and tetrachloroethane. The number of molecules and their relative orientation in supramolecular assemblies were estimated in dependence of the solvent (chloroform, tetrachloroethane) and the heating temperature. Samples fabricated after heating of the Ru ( II ) complexes solution in tetrachloroethane formed stable supramolecular wires of 600 nm and more in length. The third-order non-linear optical characteristics of complexes in tetrachloroethane solution were studied by the z-scanning method. Molecular polarizability of the complex is about 4.5 × 10-32 esu. The polarizability attributed to one molecule increases by a factor of 3.6 when the individual molecule assembles into a supramolecular aggregate.

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Grishina A. D. et al. Solvent-induced supramolecular assemblies of crown-substituted ruthenium phthalocyaninate: // Journal of Porphyrins and Phthalocyanines. 2009. Vol. 13. No. 1. pp. 92-98.
GOST all authors (up to 50) Copy
Grishina A. D., Gorbunova Y. G., Zolotarevsky V. I., Pereshivko L. Y., Enakieva Y. Y., Krivenko T. V., Savelyev V., Vannikov A. V., Tsivadze A. Y. Solvent-induced supramolecular assemblies of crown-substituted ruthenium phthalocyaninate: // Journal of Porphyrins and Phthalocyanines. 2009. Vol. 13. No. 1. pp. 92-98.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1142/S1088424609000231
UR - https://www.worldscientific.com/doi/abs/10.1142/S1088424609000231
TI - Solvent-induced supramolecular assemblies of crown-substituted ruthenium phthalocyaninate:
T2 - Journal of Porphyrins and Phthalocyanines
AU - Grishina, Antonina D.
AU - Gorbunova, Yulia G.
AU - Zolotarevsky, Victor I.
AU - Pereshivko, Larisa Ya.
AU - Enakieva, Yulia Yu.
AU - Krivenko, Tatiana V.
AU - Savelyev, Vladimir
AU - Vannikov, Anatoly V.
AU - Tsivadze, Aslan Yu.
PY - 2009
DA - 2009/01/01
PB - World Scientific
SP - 92-98
IS - 1
VL - 13
SN - 1088-4246
SN - 1099-1409
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Grishina,
author = {Antonina D. Grishina and Yulia G. Gorbunova and Victor I. Zolotarevsky and Larisa Ya. Pereshivko and Yulia Yu. Enakieva and Tatiana V. Krivenko and Vladimir Savelyev and Anatoly V. Vannikov and Aslan Yu. Tsivadze},
title = {Solvent-induced supramolecular assemblies of crown-substituted ruthenium phthalocyaninate:},
journal = {Journal of Porphyrins and Phthalocyanines},
year = {2009},
volume = {13},
publisher = {World Scientific},
month = {jan},
url = {https://www.worldscientific.com/doi/abs/10.1142/S1088424609000231},
number = {1},
pages = {92--98},
doi = {10.1142/S1088424609000231}
}
MLA
Cite this
MLA Copy
Grishina, Antonina D., et al. “Solvent-induced supramolecular assemblies of crown-substituted ruthenium phthalocyaninate:.” Journal of Porphyrins and Phthalocyanines, vol. 13, no. 1, Jan. 2009, pp. 92-98. https://www.worldscientific.com/doi/abs/10.1142/S1088424609000231.