Post-synthetic methods for functionalization of imidazole-fused porphyrins
Inna A Abdulaeva
1, 2
,
Kirill P. Birin
1
,
Yulia G. Gorbunova
1, 3
,
Aslan Yu. Tsivadze
1, 3
,
Alla Bessmertnykh-Lemeune
2
Publication type: Journal Article
Publication date: 2018-08-01
scimago Q3
wos Q4
SJR: 0.228
CiteScore: 1.8
Impact factor: 0.9
ISSN: 10884246, 10991409
General Chemistry
Abstract
Several methods for the post-synthetic modification of imidazo[4,5-[Formula: see text]]porphyrins are reported. First, a synthetic approach to the isomeric difunctionalized porphyrins, containing two [Formula: see text]-fused 2-aryl-1[Formula: see text]-imidazole cycles at adjacent or opposite pyrrole rings of the macrocycle is developed. The core chemistry of this synthetic route is the transformation of 2-aryl-1[Formula: see text]-imidazo[4,5-[Formula: see text]]porphyrins into corresponding imidazodioxochlorins followed by Debus–Radziszewski condensation with aromatic aldehyde. Next, 2-(4-bromophenyl)-1[Formula: see text]-imidazo[4,5-[Formula: see text]]-5,10,15,20-tetramesitylporphyrin was transformed into useful carboxy- and phosphonato-substituted precursors for material chemistry according to palladium-catalyzed C–C and C–P bond forming reactions.
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Total citations:
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Citations from 2024:
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(18%)
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GOST
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Abdulaeva I. A. et al. Post-synthetic methods for functionalization of imidazole-fused porphyrins // Journal of Porphyrins and Phthalocyanines. 2018. Vol. 22. No. 8. pp. 619-631.
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Abdulaeva I. A., Birin K. P., Gorbunova Y. G., Tsivadze A. Y., Bessmertnykh-Lemeune A. Post-synthetic methods for functionalization of imidazole-fused porphyrins // Journal of Porphyrins and Phthalocyanines. 2018. Vol. 22. No. 8. pp. 619-631.
Cite this
RIS
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TY - JOUR
DO - 10.1142/S1088424618500475
UR - https://www.worldscientific.com/doi/abs/10.1142/S1088424618500475
TI - Post-synthetic methods for functionalization of imidazole-fused porphyrins
T2 - Journal of Porphyrins and Phthalocyanines
AU - Abdulaeva, Inna A
AU - Birin, Kirill P.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan Yu.
AU - Bessmertnykh-Lemeune, Alla
PY - 2018
DA - 2018/08/01
PB - World Scientific
SP - 619-631
IS - 8
VL - 22
SN - 1088-4246
SN - 1099-1409
ER -
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@article{2018_Abdulaeva,
author = {Inna A Abdulaeva and Kirill P. Birin and Yulia G. Gorbunova and Aslan Yu. Tsivadze and Alla Bessmertnykh-Lemeune},
title = {Post-synthetic methods for functionalization of imidazole-fused porphyrins},
journal = {Journal of Porphyrins and Phthalocyanines},
year = {2018},
volume = {22},
publisher = {World Scientific},
month = {aug},
url = {https://www.worldscientific.com/doi/abs/10.1142/S1088424618500475},
number = {8},
pages = {619--631},
doi = {10.1142/S1088424618500475}
}
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MLA
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Abdulaeva, Inna A., et al. “Post-synthetic methods for functionalization of imidazole-fused porphyrins.” Journal of Porphyrins and Phthalocyanines, vol. 22, no. 8, Aug. 2018, pp. 619-631. https://www.worldscientific.com/doi/abs/10.1142/S1088424618500475.