Synthesis and spectral properties of ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands
Publication type: Journal Article
Publication date: 2003-12-01
scimago Q3
wos Q4
SJR: 0.228
CiteScore: 1.8
Impact factor: 0.9
ISSN: 10884246, 10991409
General Chemistry
Abstract
The synthesis of novel bis-axially coordinated ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands ( R 4 Pc ) Ru ( L 2) ( R 4Pc2- = 4,5,4',5',4'',5'', 4''',5'''- tetrakis(1,4,7,10,13-pentaoxotridecamethylene)phthalocyaninate-ion, L = pyridine (py), isoquino-line (iqnl), triethylamine ( Et 3 N )) is reported. The preparation technique involves the interaction of ( R 4 Pc ) Ru ( CO )( CH 3 OH ) with trimethylamine oxide in an N-donor solvent. The advantage of this method consists in selective carbonyl ejection from ( R 4 Pc ) Ru ( CO ) X with simultaneous substi-tution by N-donor ligands. The application of this procedure allowed us to decrease essentially the reaction time, as compared with photochemical methods, as well as to increase substantially the yield of reaction products. UV-visible, 1 H NMR, FT-IR and mass-spectrometry were used for characterization of the obtained compounds.
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GOST
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Gorbunova Y. G. et al. Synthesis and spectral properties of ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands // Journal of Porphyrins and Phthalocyanines. 2003. Vol. 7. No. 11-12. pp. 795-800.
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Gorbunova Y. G., Enakieva Y. Y., Sakharov S. G., Tsivadze A. Y. Synthesis and spectral properties of ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands // Journal of Porphyrins and Phthalocyanines. 2003. Vol. 7. No. 11-12. pp. 795-800.
Cite this
RIS
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TY - JOUR
DO - 10.1142/s1088424603000987
UR - https://www.worldscientific.com/doi/abs/10.1142/S1088424603000987
TI - Synthesis and spectral properties of ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands
T2 - Journal of Porphyrins and Phthalocyanines
AU - Gorbunova, Yuliya G.
AU - Enakieva, Yuliya Yu.
AU - Sakharov, Sergey G.
AU - Tsivadze, Aslan Yu.
PY - 2003
DA - 2003/12/01
PB - World Scientific
SP - 795-800
IS - 11-12
VL - 7
SN - 1088-4246
SN - 1099-1409
ER -
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BibTex (up to 50 authors)
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@article{2003_Gorbunova,
author = {Yuliya G. Gorbunova and Yuliya Yu. Enakieva and Sergey G. Sakharov and Aslan Yu. Tsivadze},
title = {Synthesis and spectral properties of ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands},
journal = {Journal of Porphyrins and Phthalocyanines},
year = {2003},
volume = {7},
publisher = {World Scientific},
month = {dec},
url = {https://www.worldscientific.com/doi/abs/10.1142/S1088424603000987},
number = {11-12},
pages = {795--800},
doi = {10.1142/s1088424603000987}
}
Cite this
MLA
Copy
Gorbunova, Yuliya G., et al. “Synthesis and spectral properties of ruthenium(II) complexes with tetra-15-crown-5-phthalocyanine and N-donor ligands.” Journal of Porphyrins and Phthalocyanines, vol. 7, no. 11-12, Dec. 2003, pp. 795-800. https://www.worldscientific.com/doi/abs/10.1142/S1088424603000987.