World Scientific
Journal of Porphyrins and Phthalocyanines
,  том 13 ,  издание 8-9 ,  страницы 859-864

Behavior of aluminum(III)-tetra-15-crown-5-phthalocyaninates in organic media by fluorescence and UV-visible spectroscopy

Тип публикации: Journal Article
Дата публикации: 2009-08-01
World Scientific
SCImago Q3
WOS Q4
БС2
SJR: 0.227
CiteScore: 1.7
Impact factor: 1
ISSN: 10884246, 10991409
General Chemistry
Краткое описание

The results of a UV-vis and fluorescent spectral investigation of a tetra-15-crown-5-substituted aluminum phthalocyanine [ (R4Pc)Al(OH) ] (1), where (R4Pc)2- = 2,3,9,10,16,17,24,25-tetrakis(15-crown-5)phthalocyaninate-dianion, in different solvents (CHCl3, DMSO, MeOH) are reported. It was shown that compound exhibits a very strong tendency to aggregation with the formation of μ-fluoro dimer [((R4Pc)Al)2F]+ in the presence of F - in the low-donor solvent CHCl3 . This complex is not emissive. The formation of two different emissive species [(R4Pc)AlF2]- and [(R4Pc)Al(OH)2]- during the reaction of 1 with anions ( F - and OH - correspondently) in high-donor DMSO was established.

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ГОСТ |
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Lapkina L. A. et al. Behavior of aluminum(III)-tetra-15-crown-5-phthalocyaninates in organic media by fluorescence and UV-visible spectroscopy // Journal of Porphyrins and Phthalocyanines. 2009. Vol. 13. No. 8-9. pp. 859-864.
ГОСТ со всеми авторами (до 50) Скопировать
Lapkina L. A., Konstantinov N. Y., LARCHENKO V. E., Gorbunova Y. G., Tsivadze A. Yu. Behavior of aluminum(III)-tetra-15-crown-5-phthalocyaninates in organic media by fluorescence and UV-visible spectroscopy // Journal of Porphyrins and Phthalocyanines. 2009. Vol. 13. No. 8-9. pp. 859-864.
RIS |
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TY - JOUR
DO - 10.1142/s108842460900005x
UR - https://www.worldscientific.com/doi/abs/10.1142/S108842460900005X
TI - Behavior of aluminum(III)-tetra-15-crown-5-phthalocyaninates in organic media by fluorescence and UV-visible spectroscopy
T2 - Journal of Porphyrins and Phthalocyanines
AU - Lapkina, Lyudmila A.
AU - Konstantinov, Nikita Yu.
AU - LARCHENKO, VLADIMIR E.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan Yu
PY - 2009
DA - 2009/08/01
PB - World Scientific
SP - 859-864
IS - 8-9
VL - 13
SN - 1088-4246
SN - 1099-1409
ER -
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@article{2009_Lapkina,
author = {Lyudmila A. Lapkina and Nikita Yu. Konstantinov and VLADIMIR E. LARCHENKO and Yulia G. Gorbunova and Aslan Yu Tsivadze},
title = {Behavior of aluminum(III)-tetra-15-crown-5-phthalocyaninates in organic media by fluorescence and UV-visible spectroscopy},
journal = {Journal of Porphyrins and Phthalocyanines},
year = {2009},
volume = {13},
publisher = {World Scientific},
month = {aug},
url = {https://www.worldscientific.com/doi/abs/10.1142/S108842460900005X},
number = {8-9},
pages = {859--864},
doi = {10.1142/s108842460900005x}
}
MLA
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MLA Скопировать
Lapkina, Lyudmila A., et al. “Behavior of aluminum(III)-tetra-15-crown-5-phthalocyaninates in organic media by fluorescence and UV-visible spectroscopy.” Journal of Porphyrins and Phthalocyanines, vol. 13, no. 8-9, Aug. 2009, pp. 859-864. https://www.worldscientific.com/doi/abs/10.1142/S108842460900005X.
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