volume 67 issue 1 pages 19-40

Vacuum Ultraviolet Photoionization of Complex Chemical Systems

Publication typeJournal Article
Publication date2016-05-27
scimago Q1
wos Q1
SJR2.779
CiteScore15.2
Impact factor11.7
ISSN0066426X, 15451593
Physical and Theoretical Chemistry
Abstract

Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the study of complex chemical systems. The identification of novel reactive intermediates and radicals is revealed in flame, pulsed photolysis, and pyrolysis reactors, leading to the elucidation of spectroscopy, reaction mechanisms, and kinetics. Mass-resolved threshold photoelectron photoion coincidence measurements provide unprecedented access to vibrationally resolved spectra of free radicals present in high-temperature reactors. Photoionization measurements in water clusters, nucleic acid base dimers, and their complexes with water provide signatures of proton transfer in hydrogen-bonded and π-stacked systems. Experimental and theoretical methods to track ion–molecule reactions and fragmentation pathways in intermolecular and intramolecular hydrogen-bonded systems in sugars and alcohols are described. Photoionization of laser-ablated molecules, clusters, and their reaction products inform thermodynamics and spectroscopy that are relevant to astrochemistry and catalysis. New directions in coupling VUV radiation to interrogate complex chemical systems are discussed.

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GOST |
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GOST Copy
Kostko O., Bandyopadhyay B., Ahmed M. Vacuum Ultraviolet Photoionization of Complex Chemical Systems // Annual Review of Physical Chemistry. 2016. Vol. 67. No. 1. pp. 19-40.
GOST all authors (up to 50) Copy
Kostko O., Bandyopadhyay B., Ahmed M. Vacuum Ultraviolet Photoionization of Complex Chemical Systems // Annual Review of Physical Chemistry. 2016. Vol. 67. No. 1. pp. 19-40.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1146/annurev-physchem-040215-112553
UR - https://doi.org/10.1146/annurev-physchem-040215-112553
TI - Vacuum Ultraviolet Photoionization of Complex Chemical Systems
T2 - Annual Review of Physical Chemistry
AU - Kostko, Oleg
AU - Bandyopadhyay, Biswajit
AU - Ahmed, Musahid
PY - 2016
DA - 2016/05/27
PB - Annual Reviews
SP - 19-40
IS - 1
VL - 67
PMID - 26980311
SN - 0066-426X
SN - 1545-1593
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Kostko,
author = {Oleg Kostko and Biswajit Bandyopadhyay and Musahid Ahmed},
title = {Vacuum Ultraviolet Photoionization of Complex Chemical Systems},
journal = {Annual Review of Physical Chemistry},
year = {2016},
volume = {67},
publisher = {Annual Reviews},
month = {may},
url = {https://doi.org/10.1146/annurev-physchem-040215-112553},
number = {1},
pages = {19--40},
doi = {10.1146/annurev-physchem-040215-112553}
}
MLA
Cite this
MLA Copy
Kostko, Oleg, et al. “Vacuum Ultraviolet Photoionization of Complex Chemical Systems.” Annual Review of Physical Chemistry, vol. 67, no. 1, May. 2016, pp. 19-40. https://doi.org/10.1146/annurev-physchem-040215-112553.