Highly Fluorescent Noble-Metal Quantum Dots
Publication type: Journal Article
Publication date: 2007-05-01
scimago Q1
wos Q1
SJR: 2.779
CiteScore: 15.2
Impact factor: 11.7
ISSN: 0066426X, 15451593
PubMed ID:
17105412
Physical and Theoretical Chemistry
Abstract
Highly fluorescent, water-soluble, few-atom noble-metal quantum dots have been created that behave as multielectron artificial atoms with discrete, size-tunable electronic transitions throughout the visible and near infrared. These molecular metals exhibit highly polarizable transitions and scale in size according to the simple relation EFermi/N1/3, predicted by the free-electron model of metallic behavior. This simple scaling indicates that fluorescence arises from intraband transitions of free electrons, and these conduction-electron transitions are the low-number limit of the plasmon—the collective dipole oscillations occurring when a continuous density of states is reached. Providing the missing link between atomic and nanoparticle behavior in noble metals, these emissive, water-soluble Au nanoclusters open new opportunities for biological labels, energy-transfer pairs, and light-emitting sources in nanoscale optoelectronics.
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1.2k
Total citations:
1212
Citations from 2025:
30
(2.48%)
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GOST
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Zheng J., Nicovich P. R., Dickson R. M. Highly Fluorescent Noble-Metal Quantum Dots // Annual Review of Physical Chemistry. 2007. Vol. 58. No. 1. pp. 409-431.
GOST all authors (up to 50)
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Zheng J., Nicovich P. R., Dickson R. M. Highly Fluorescent Noble-Metal Quantum Dots // Annual Review of Physical Chemistry. 2007. Vol. 58. No. 1. pp. 409-431.
Cite this
RIS
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TY - JOUR
DO - 10.1146/annurev.physchem.58.032806.104546
UR - https://doi.org/10.1146/annurev.physchem.58.032806.104546
TI - Highly Fluorescent Noble-Metal Quantum Dots
T2 - Annual Review of Physical Chemistry
AU - Zheng, Jie
AU - Nicovich, Philip R
AU - Dickson, Robert M
PY - 2007
DA - 2007/05/01
PB - Annual Reviews
SP - 409-431
IS - 1
VL - 58
PMID - 17105412
SN - 0066-426X
SN - 1545-1593
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_Zheng,
author = {Jie Zheng and Philip R Nicovich and Robert M Dickson},
title = {Highly Fluorescent Noble-Metal Quantum Dots},
journal = {Annual Review of Physical Chemistry},
year = {2007},
volume = {58},
publisher = {Annual Reviews},
month = {may},
url = {https://doi.org/10.1146/annurev.physchem.58.032806.104546},
number = {1},
pages = {409--431},
doi = {10.1146/annurev.physchem.58.032806.104546}
}
Cite this
MLA
Copy
Zheng, Jie, et al. “Highly Fluorescent Noble-Metal Quantum Dots.” Annual Review of Physical Chemistry, vol. 58, no. 1, May. 2007, pp. 409-431. https://doi.org/10.1146/annurev.physchem.58.032806.104546.