Electrochemical and Solid-State Letters, volume 2, issue 1, pages 12
Investigation of Enhanced CO Tolerance in Proton Exchange Membrane Fuel Cells by Carbon Supported PtMo Alloy Catalyst
Publication type: Journal Article
Publication date: 2002-07-28
Quartile SCImago
— Quartile WOS
—
Impact factor: —
ISSN: 10990062, 19448775
Physical and Theoretical Chemistry
General Chemical Engineering
Electrochemistry
General Materials Science
Electrical and Electronic Engineering
Abstract
E-TEK, Incorporated, Natick, Massachusetts 01760, USAWe report a two- to threefold enhancement of CO tolerance in a proton exchange membrane (PEM) fuel cell, exhibited by carbonsupported nanocrystalline PtMo/C as compared to the current state of the art PtRu/C electrocatalysts. The bulk of these nanocrys-tals were comprised of Pt alloyed with Mo in the ratio 8.7:1.3 as shown by both X-ray diffraction and in situ extended X-ray ab sorp-tion fine structure measurements. Rotating disk electrode measurements and cyclic voltammetry in a PEM fuel cell indicate theonset of CO oxidation at potentials as low as 0.1 V. Further, the oxidation of CO exhibits two distinct peaks, indicating redox b ehav-ior involving oxyhydroxides of Mo. This is supported by in situ X-ray absorption near edge structure measurements at the Mo Kedge.© 1999 The Electrochemical Society. S1099-0062(98)08-029-8. All rights reserved.Manuscript submitted August 10, 1998; revised manuscript received September 28, 1998. Available electronically October 30, 1998.
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- Statistics recalculated weekly.
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Mukerjee S. Investigation of Enhanced CO Tolerance in Proton Exchange Membrane Fuel Cells by Carbon Supported PtMo Alloy Catalyst // Electrochemical and Solid-State Letters. 2002. Vol. 2. No. 1. p. 12.
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Mukerjee S. Investigation of Enhanced CO Tolerance in Proton Exchange Membrane Fuel Cells by Carbon Supported PtMo Alloy Catalyst // Electrochemical and Solid-State Letters. 2002. Vol. 2. No. 1. p. 12.
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TY - JOUR
DO - 10.1149/1.1390718
UR - https://doi.org/10.1149/1.1390718
TI - Investigation of Enhanced CO Tolerance in Proton Exchange Membrane Fuel Cells by Carbon Supported PtMo Alloy Catalyst
T2 - Electrochemical and Solid-State Letters
AU - Mukerjee, S.
PY - 2002
DA - 2002/07/28 00:00:00
PB - The Electrochemical Society
SP - 12
IS - 1
VL - 2
SN - 1099-0062
SN - 1944-8775
ER -
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@article{2002_Mukerjee,
author = {S. Mukerjee},
title = {Investigation of Enhanced CO Tolerance in Proton Exchange Membrane Fuel Cells by Carbon Supported PtMo Alloy Catalyst},
journal = {Electrochemical and Solid-State Letters},
year = {2002},
volume = {2},
publisher = {The Electrochemical Society},
month = {jul},
url = {https://doi.org/10.1149/1.1390718},
number = {1},
pages = {12},
doi = {10.1149/1.1390718}
}
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Mukerjee, S.. “Investigation of Enhanced CO Tolerance in Proton Exchange Membrane Fuel Cells by Carbon Supported PtMo Alloy Catalyst.” Electrochemical and Solid-State Letters, vol. 2, no. 1, Jul. 2002, p. 12. https://doi.org/10.1149/1.1390718.