Journal of the Electrochemical Society, volume 158, issue 5, pages E45
Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces
Minh-Tung Le
1
,
M. Ren
1
,
Ziyu Zhang
2
,
Phillip T. Sprunger
2
,
Richard J. Kurtz
2
,
J. C. Flake
1
1
aGordon and Mary Cain Department of Chemical Engineering,
Publication type: Journal Article
Publication date: 2011-03-25
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.9
ISSN: 00134651, 19457111
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Renewable Energy, Sustainability and the Environment
Abstract
The direct reduction of CO2 to CH3OH is known to occur at several types of electrocatalysts including oxidized Cu electrodes. In this work, we examine the yield behavior of an electrodeposited cuprous oxide thin film and explore relationships between surface chemistry and reaction behavior relative to air-oxidized and anodized Cu electrodes. CH3OH yields (43 μmol cm-2 h-1) and Faradaic efficiencies (38%) observed at cuprous oxide electrodes were remarkably higher than air-oxidized or anodized Cu electrodes suggesting Cu(I) species may play a critical role in selectivity to CH3OH. Experimental results also show CH3OH yields are dynamic and the copper oxides are reduced to metallic Cu in a simultaneous process. Yield behavior is discussed in comparison with photoelectrochemical and hydrogenation reactions where the improved stability of Cu(I) species may allow continuous CH3OH generation.
Top-30
Journals
|
2
4
6
8
10
12
14
16
18
|
|
|
Journal of Physical Chemistry C
17 publications, 3.88%
|
|
|
Journal of Materials Chemistry A
13 publications, 2.97%
|
|
|
Journal of CO2 Utilization
12 publications, 2.74%
|
|
|
Journal of the Electrochemical Society
11 publications, 2.51%
|
|
|
ACS Catalysis
10 publications, 2.28%
|
|
|
Applied Catalysis B: Environmental
9 publications, 2.05%
|
|
|
Angewandte Chemie - International Edition
9 publications, 2.05%
|
|
|
Angewandte Chemie
9 publications, 2.05%
|
|
|
ChemSusChem
9 publications, 2.05%
|
|
|
Physical Chemistry Chemical Physics
9 publications, 2.05%
|
|
|
Journal of the American Chemical Society
8 publications, 1.83%
|
|
|
RSC Advances
8 publications, 1.83%
|
|
|
Electrochimica Acta
7 publications, 1.6%
|
|
|
ACS applied materials & interfaces
7 publications, 1.6%
|
|
|
Catalysis Today
6 publications, 1.37%
|
|
|
ACS Sustainable Chemistry and Engineering
6 publications, 1.37%
|
|
|
Chemical Society Reviews
6 publications, 1.37%
|
|
|
Nature Communications
5 publications, 1.14%
|
|
|
Journal of Energy Chemistry
5 publications, 1.14%
|
|
|
International Journal of Hydrogen Energy
5 publications, 1.14%
|
|
|
Journal of Catalysis
5 publications, 1.14%
|
|
|
Journal of Electroanalytical Chemistry
5 publications, 1.14%
|
|
|
ChemCatChem
5 publications, 1.14%
|
|
|
Nanomaterials
4 publications, 0.91%
|
|
|
Chemical Engineering Journal
4 publications, 0.91%
|
|
|
Journal of Power Sources
4 publications, 0.91%
|
|
|
Applied Surface Science
4 publications, 0.91%
|
|
|
Advanced Materials
4 publications, 0.91%
|
|
|
ChemElectroChem
4 publications, 0.91%
|
|
|
2
4
6
8
10
12
14
16
18
|
Publishers
|
20
40
60
80
100
120
140
|
|
|
Elsevier
132 publications, 30.14%
|
|
|
Wiley
80 publications, 18.26%
|
|
|
American Chemical Society (ACS)
74 publications, 16.89%
|
|
|
Royal Society of Chemistry (RSC)
62 publications, 14.16%
|
|
|
Springer Nature
26 publications, 5.94%
|
|
|
The Electrochemical Society
13 publications, 2.97%
|
|
|
MDPI
8 publications, 1.83%
|
|
|
Taylor & Francis
7 publications, 1.6%
|
|
|
AIP Publishing
3 publications, 0.68%
|
|
|
IOP Publishing
3 publications, 0.68%
|
|
|
American Physical Society (APS)
2 publications, 0.46%
|
|
|
2 publications, 0.46%
|
|
|
2 publications, 0.46%
|
|
|
ASME International
1 publication, 0.23%
|
|
|
Physical Society of Japan
1 publication, 0.23%
|
|
|
Frontiers Media S.A.
1 publication, 0.23%
|
|
|
King Saud University
1 publication, 0.23%
|
|
|
Walter de Gruyter
1 publication, 0.23%
|
|
|
American Association for the Advancement of Science (AAAS)
1 publication, 0.23%
|
|
|
Hindawi Limited
1 publication, 0.23%
|
|
|
Annual Reviews
1 publication, 0.23%
|
|
|
IntechOpen
1 publication, 0.23%
|
|
|
CSIRO Publishing
1 publication, 0.23%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.23%
|
|
|
20
40
60
80
100
120
140
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Le M. et al. Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces // Journal of the Electrochemical Society. 2011. Vol. 158. No. 5. p. E45.
GOST all authors (up to 50)
Copy
Le M., Ren M., Zhang Z., Zhang Z., Sprunger P. T., Kurtz R. J., Flake J. C. Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces // Journal of the Electrochemical Society. 2011. Vol. 158. No. 5. p. E45.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1149/1.3561636
UR - https://doi.org/10.1149/1.3561636
TI - Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces
T2 - Journal of the Electrochemical Society
AU - Ren, M.
AU - Zhang, Z
AU - Le, Minh-Tung
AU - Zhang, Ziyu
AU - Sprunger, Phillip T.
AU - Kurtz, Richard J.
AU - Flake, J. C.
PY - 2011
DA - 2011/03/25
PB - The Electrochemical Society
SP - E45
IS - 5
VL - 158
SN - 0013-4651
SN - 1945-7111
ER -
Cite this
BibTex
Copy
@article{2011_Le,
author = {M. Ren and Z Zhang and Minh-Tung Le and Ziyu Zhang and Phillip T. Sprunger and Richard J. Kurtz and J. C. Flake},
title = {Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces},
journal = {Journal of the Electrochemical Society},
year = {2011},
volume = {158},
publisher = {The Electrochemical Society},
month = {mar},
url = {https://doi.org/10.1149/1.3561636},
number = {5},
pages = {E45},
doi = {10.1149/1.3561636}
}
Cite this
MLA
Copy
Le, Minh-Tung, et al. “Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces.” Journal of the Electrochemical Society, vol. 158, no. 5, Mar. 2011, p. E45. https://doi.org/10.1149/1.3561636.
Profiles