Journal of the Electrochemical Society, volume 162, issue 1, pages F190-F203
Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media
Publication type: Journal Article
Publication date: 2014-12-06
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.9
ISSN: 00134651, 19457111
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Renewable Energy, Sustainability and the Environment
Abstract
The hydrogen oxidation and evolution reaction (HOR/HER) behavior of carbon supported metal (Pt, Ir, Rh, Pd) nanoparticle electrocatalysts is studied using the H2 pump approach, in a proton exchange membrane fuel cell (PEMFC) setup. After describing the best method for normalizing the net faradaic currents to the active surface area of the electrodes, we measure the HOR/HER kinetic parameters (exchange current densities and transfer coefficients) in a temperature range from 313 K to 353 K and calculate the activation energy for the HOR/HER process. We compare the measured kinetic parameters with those extracted from different mass-transport limitation free setups in literature, to evaluate the hydrogen electrocatalysis on these most active surfaces. The HOR/HER activity scales with the following: Pt > Ir Rh > Pd. The anodic and cathodic transfer coefficients are similar for all metals (ca. 0.5), leading to Tafel slopes of ca. 140 mV/decade at 353 K (except for the anodic branch of Pd and the cathodic branch of Rh). The lowest activation energies are found for Pt and Ir (≈20 kJ/mol). For Rh and Pd, higher activation energies are found (≈30 kJ/mol), and attributed to the formation of surface oxides and hydride phase, respectively. © The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. [DOI: 10.1149/2.0981501jes] All rights reserved.
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Durst J. et al. Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media // Journal of the Electrochemical Society. 2014. Vol. 162. No. 1. p. F190-F203.
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Durst J., Simon C., Hasché F., Gasteiger H. A. Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media // Journal of the Electrochemical Society. 2014. Vol. 162. No. 1. p. F190-F203.
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TY - JOUR
DO - 10.1149/2.0981501jes
UR - https://doi.org/10.1149/2.0981501jes
TI - Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media
T2 - Journal of the Electrochemical Society
AU - Durst, Julien
AU - Simon, Christoph
AU - Hasché, Frédéric
AU - Gasteiger, Hubert A.
PY - 2014
DA - 2014/12/06 00:00:00
PB - The Electrochemical Society
SP - F190-F203
IS - 1
VL - 162
SN - 0013-4651
SN - 1945-7111
ER -
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@article{2014_Durst,
author = {Julien Durst and Christoph Simon and Frédéric Hasché and Hubert A. Gasteiger},
title = {Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media},
journal = {Journal of the Electrochemical Society},
year = {2014},
volume = {162},
publisher = {The Electrochemical Society},
month = {dec},
url = {https://doi.org/10.1149/2.0981501jes},
number = {1},
pages = {F190--F203},
doi = {10.1149/2.0981501jes}
}
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Durst, Julien, et al. “Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media.” Journal of the Electrochemical Society, vol. 162, no. 1, Dec. 2014, pp. F190-F203. https://doi.org/10.1149/2.0981501jes.