Nucleation Effect of the Chemical Structure of Alkylammonium Salt on the Crystallization Behavior of Poly(Vinylidene Fluoride)

We investigated the effect of the chemical structure of alkylammonium salt on the crystallization behavior of poly(vinylidene fluoride) (PVDF) by DSC, optical microscopy, light scattering, and FT-IR. The nonisothermal and isothermal crystallizations of PVDF were accelerated by adding alkylammonium salt consisting of short alkyl chains and small anion species, and the spherulite size and the ordering in the spherulite became smaller due to the nucleation agent effect. The FT-IR spectra revealed that electroactive γ-phase was preferentially formed by adding alkylammonium salts though the accelerated crystallization was suppressed due to the steric hindrance effect by the long alkyl chain and large anion species. On the other hand, the formation of the γ-phase was suppressed when the dispersion of the salt in the PVDF matrix was poor due to the high melting temperature.