Open Access
Synthesis, Characterization, Mössbauer Parameters, and Antitumor Activity of Fe(III) Curcumin Complex
Тип публикации: Journal Article
Дата публикации: 2013-11-10
SCImago Q1
WOS Q1
БС1
SJR: 0.816
CiteScore: 15.4
Impact factor: 4.1
ISSN: 15653633, 1687479X
PubMed ID:
23606821
Organic Chemistry
Biochemistry
Inorganic Chemistry
Краткое описание
Curcumin-Fe(III) complex was prepared from Fe(NO3)3·9H2O precursor and curcumin by refluxing a slightly basic methanolic solution of their mixture with the objective of investigating its cytotoxicity. The enol form of curcumin ligand was established by FTIR, UV/Vis,1H NMR, and13C NMR spectroscopy. The as-prepared product was characterized by elemental analysis, FTIR, UV, and Mössbauer spectroscopic techniques. An octahedral high-spin Fe(III) complex was obtained,δ, 0.37 mms−1; Q.S., 0.79 mms−1; no magnetic relaxation was observed at liquid N2temperature, neither reduction of Fe(III). The tested cytotoxicity of the as-prepared complex on four cancer cell lines indicated inhibition of the curcumin activity upon complexing with iron.
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Khalil M. I., Al Zahem A. M., Al Qunaibit M. H. Synthesis, Characterization, Mössbauer Parameters, and Antitumor Activity of Fe(III) Curcumin Complex // Bioinorganic Chemistry and Applications. 2013. Vol. 2013. pp. 1-5.
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Khalil M. I., Al Zahem A. M., Al Qunaibit M. H. Synthesis, Characterization, Mössbauer Parameters, and Antitumor Activity of Fe(III) Curcumin Complex // Bioinorganic Chemistry and Applications. 2013. Vol. 2013. pp. 1-5.
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TY - JOUR
DO - 10.1155/2013/982423
UR - https://doi.org/10.1155/2013/982423
TI - Synthesis, Characterization, Mössbauer Parameters, and Antitumor Activity of Fe(III) Curcumin Complex
T2 - Bioinorganic Chemistry and Applications
AU - Khalil, Mutasim Ibrahim
AU - Al Zahem, Aisha Mohamed
AU - Al Qunaibit, Maha Hamad
PY - 2013
DA - 2013/11/10
PB - Hindawi Limited
SP - 1-5
VL - 2013
PMID - 23606821
SN - 1565-3633
SN - 1687-479X
ER -
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@article{2013_Khalil,
author = {Mutasim Ibrahim Khalil and Aisha Mohamed Al Zahem and Maha Hamad Al Qunaibit},
title = {Synthesis, Characterization, Mössbauer Parameters, and Antitumor Activity of Fe(III) Curcumin Complex},
journal = {Bioinorganic Chemistry and Applications},
year = {2013},
volume = {2013},
publisher = {Hindawi Limited},
month = {nov},
url = {https://doi.org/10.1155/2013/982423},
pages = {1--5},
doi = {10.1155/2013/982423}
}
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