A New Synthetic Method for Methyl Dihydrojasmonate from a Butadiene Telomer
Publication type: Journal Article
Publication date: 1979-01-01
scimago Q2
wos Q2
SJR: 0.678
CiteScore: 7.0
Impact factor: 3.8
ISSN: 00092673, 13480634
General Chemistry
Abstract
Ethyl 2-acetyl-4, 9-decadienoate, easily obtained by the palladium catalyzed telomerization of butadiene with ethyl acetoacetate, was selectively hydrogenated to ethyl 2-acetyl-9-decenoate using RuCl2 (PPh3)3 as a catalyst. Deacetylation, followed by hydrolysis produced 4-decenoic acid, which was converted into acid chloride. The AlCl3-promoted cyclization gave 2-pentyl-2-cyclopentenone, from which methyl dihydrojasmonate was prepared.
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GOST
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Tsuji J., Kasuga K., Takahashi T. A New Synthetic Method for Methyl Dihydrojasmonate from a Butadiene Telomer // Bulletin of the Chemical Society of Japan. 1979. Vol. 52. No. 1. pp. 216-217.
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Tsuji J., Kasuga K., Takahashi T. A New Synthetic Method for Methyl Dihydrojasmonate from a Butadiene Telomer // Bulletin of the Chemical Society of Japan. 1979. Vol. 52. No. 1. pp. 216-217.
Cite this
RIS
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TY - JOUR
DO - 10.1246/bcsj.52.216
UR - https://doi.org/10.1246/bcsj.52.216
TI - A New Synthetic Method for Methyl Dihydrojasmonate from a Butadiene Telomer
T2 - Bulletin of the Chemical Society of Japan
AU - Tsuji, Jiro
AU - Kasuga, Kazuyuki
AU - Takahashi, Takashi
PY - 1979
DA - 1979/01/01
PB - Oxford University Press
SP - 216-217
IS - 1
VL - 52
SN - 0009-2673
SN - 1348-0634
ER -
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BibTex (up to 50 authors)
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@article{1979_Tsuji,
author = {Jiro Tsuji and Kazuyuki Kasuga and Takashi Takahashi},
title = {A New Synthetic Method for Methyl Dihydrojasmonate from a Butadiene Telomer},
journal = {Bulletin of the Chemical Society of Japan},
year = {1979},
volume = {52},
publisher = {Oxford University Press},
month = {jan},
url = {https://doi.org/10.1246/bcsj.52.216},
number = {1},
pages = {216--217},
doi = {10.1246/bcsj.52.216}
}
Cite this
MLA
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Tsuji, Jiro, et al. “A New Synthetic Method for Methyl Dihydrojasmonate from a Butadiene Telomer.” Bulletin of the Chemical Society of Japan, vol. 52, no. 1, Jan. 1979, pp. 216-217. https://doi.org/10.1246/bcsj.52.216.