Hydrodimerization of Methyl Acrylate Catalyzed by Halogenotris(triphenylphosphine)cobalt
Publication type: Journal Article
Publication date: 1981-04-01
scimago Q2
wos Q2
SJR: 0.678
CiteScore: 7.0
Impact factor: 3.8
ISSN: 00092673, 13480634
General Chemistry
Abstract
Methyl acrylate was hydrodimerized in a methanolic solution by CoX(PPh3)3 (X=halogen) into dimethyl adipate. The in situ prepared cobalt complexes from cobalt halides, triphenylphosphine, and zinc gave higher yields of the hydrodimer in the presence of alkali halides. A mechanism is proposed which involves the protonation of Co(I)–methyl acrylate π-complex to give (2-methoxycarbonylethyl)cobalt complex, followed by a further addition of methyl acrylate.
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Total citations:
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Citations from 2024:
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GOST
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Kanai H., Ishii K. Hydrodimerization of Methyl Acrylate Catalyzed by Halogenotris(triphenylphosphine)cobalt // Bulletin of the Chemical Society of Japan. 1981. Vol. 54. No. 4. pp. 1015-1018.
GOST all authors (up to 50)
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Kanai H., Ishii K. Hydrodimerization of Methyl Acrylate Catalyzed by Halogenotris(triphenylphosphine)cobalt // Bulletin of the Chemical Society of Japan. 1981. Vol. 54. No. 4. pp. 1015-1018.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1246/bcsj.54.1015
UR - https://doi.org/10.1246/bcsj.54.1015
TI - Hydrodimerization of Methyl Acrylate Catalyzed by Halogenotris(triphenylphosphine)cobalt
T2 - Bulletin of the Chemical Society of Japan
AU - Kanai, Hiroyoshi
AU - Ishii, Keiji
PY - 1981
DA - 1981/04/01
PB - Oxford University Press
SP - 1015-1018
IS - 4
VL - 54
SN - 0009-2673
SN - 1348-0634
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1981_Kanai,
author = {Hiroyoshi Kanai and Keiji Ishii},
title = {Hydrodimerization of Methyl Acrylate Catalyzed by Halogenotris(triphenylphosphine)cobalt},
journal = {Bulletin of the Chemical Society of Japan},
year = {1981},
volume = {54},
publisher = {Oxford University Press},
month = {apr},
url = {https://doi.org/10.1246/bcsj.54.1015},
number = {4},
pages = {1015--1018},
doi = {10.1246/bcsj.54.1015}
}
Cite this
MLA
Copy
Kanai, Hiroyoshi, and Keiji Ishii. “Hydrodimerization of Methyl Acrylate Catalyzed by Halogenotris(triphenylphosphine)cobalt.” Bulletin of the Chemical Society of Japan, vol. 54, no. 4, Apr. 1981, pp. 1015-1018. https://doi.org/10.1246/bcsj.54.1015.