volume 83 issue 9 pages 1781-1788

Straightforward synthesis of five-membered metallacycloallenes: 1-Zirconacyclopenta-2,3-diene compounds derived from 1,3-enynes

Publication typeJournal Article
Publication date2011-07-07
scimago Q2
wos Q3
SJR0.426
CiteScore3.2
Impact factor2.0
ISSN00334545, 13653075
General Chemistry
General Chemical Engineering
Abstract

A five-membered metallacycloallene complex, 1-zirconacyclopenta-2,3-diene, was prepared from low-valent zirconocene and 2,4-bis(trimethylsilyl)but-1-en-3-yne. The complex reacted with carbonyl compounds to afford alkynyl alcohols after hydrolysis via C=O insertion into Zr–C bond. Similarly, nitriles inserted into the Zr–C bond to give the corresponding ketones after hydrolysis. The insertion of C=O and CN selectively took place at zirconium-sp3 carbon of the metallacycle.

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GOST Copy
Suzuki N. et al. Straightforward synthesis of five-membered metallacycloallenes: 1-Zirconacyclopenta-2,3-diene compounds derived from 1,3-enynes // Pure and Applied Chemistry. 2011. Vol. 83. No. 9. pp. 1781-1788.
GOST all authors (up to 50) Copy
Suzuki N., Shimura T., Sakaguchi Y., Masuyama Y. Straightforward synthesis of five-membered metallacycloallenes: 1-Zirconacyclopenta-2,3-diene compounds derived from 1,3-enynes // Pure and Applied Chemistry. 2011. Vol. 83. No. 9. pp. 1781-1788.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1351/pac-con-11-01-14
UR - https://doi.org/10.1351/pac-con-11-01-14
TI - Straightforward synthesis of five-membered metallacycloallenes: 1-Zirconacyclopenta-2,3-diene compounds derived from 1,3-enynes
T2 - Pure and Applied Chemistry
AU - Suzuki, Noriyuki
AU - Shimura, Taichiro
AU - Sakaguchi, Yoshio
AU - Masuyama, Yoshiro
PY - 2011
DA - 2011/07/07
PB - Walter de Gruyter
SP - 1781-1788
IS - 9
VL - 83
SN - 0033-4545
SN - 1365-3075
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Suzuki,
author = {Noriyuki Suzuki and Taichiro Shimura and Yoshio Sakaguchi and Yoshiro Masuyama},
title = {Straightforward synthesis of five-membered metallacycloallenes: 1-Zirconacyclopenta-2,3-diene compounds derived from 1,3-enynes},
journal = {Pure and Applied Chemistry},
year = {2011},
volume = {83},
publisher = {Walter de Gruyter},
month = {jul},
url = {https://doi.org/10.1351/pac-con-11-01-14},
number = {9},
pages = {1781--1788},
doi = {10.1351/pac-con-11-01-14}
}
MLA
Cite this
MLA Copy
Suzuki, Noriyuki, et al. “Straightforward synthesis of five-membered metallacycloallenes: 1-Zirconacyclopenta-2,3-diene compounds derived from 1,3-enynes.” Pure and Applied Chemistry, vol. 83, no. 9, Jul. 2011, pp. 1781-1788. https://doi.org/10.1351/pac-con-11-01-14.