,
volume 63
,
issue 3
,
pages 267-274
Benzyl Complexes of Lanthanide(II) and Lanthanide(III) Metals: Trends and Comparisons
Publication type: Journal Article
Publication date: 2008-03-01
scimago Q3
wos Q4
SJR: 0.259
CiteScore: 1.5
Impact factor: 0.8
ISSN: 09320776, 18657117
General Chemistry
Abstract
A variety of benzyllanthanide complexes have been prepared by the metathesis reaction of benzylpotassium precursors with lanthanide halides. Syntheses and crystal structures for the following complexes are described: [2-Me2N-α-Me3Si-benzyl]2Eu(II)·(THF)2 (1-Eu), (2-Me2Nbenzyl) 3Ln(III) (2-Ln with Ln = Nd, Sm, Dy, Ho, Yb), (4-R-C6H4CH2)3Ln·(THF)3 (3-Y: Ln = Y, R = H; 3-La: Ln = La, R = tBu). Complexes of types 1 and 2 are thermally robust on account of a stabilization by a benzylic Me3Si substituent and/or intramolecular coordination of the Me2N substituent. Comparison of the crystal structures of these new series of lanthanide complexes shows several similarities and trends. In addition, comparisons with alkali metal and alkaline earth metal benzyl complexes are made.
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GOST
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Harder S. et al. Benzyl Complexes of Lanthanide(II) and Lanthanide(III) Metals: Trends and Comparisons // Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2008. Vol. 63. No. 3. pp. 267-274.
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Harder S., Ruspic C., Bhriain N. N., Berkermann F., Schurmann M. Benzyl Complexes of Lanthanide(II) and Lanthanide(III) Metals: Trends and Comparisons // Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2008. Vol. 63. No. 3. pp. 267-274.
Cite this
RIS
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TY - JOUR
DO - 10.1515/znb-2008-0307
UR - https://www.degruyter.com/document/doi/10.1515/znb-2008-0307/html
TI - Benzyl Complexes of Lanthanide(II) and Lanthanide(III) Metals: Trends and Comparisons
T2 - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
AU - Harder, Sjoerd
AU - Ruspic, Christian
AU - Bhriain, Nollaig Ní
AU - Berkermann, Frederic
AU - Schurmann, Markus
PY - 2008
DA - 2008/03/01
PB - Walter de Gruyter
SP - 267-274
IS - 3
VL - 63
SN - 0932-0776
SN - 1865-7117
ER -
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@article{2008_Harder,
author = {Sjoerd Harder and Christian Ruspic and Nollaig Ní Bhriain and Frederic Berkermann and Markus Schurmann},
title = {Benzyl Complexes of Lanthanide(II) and Lanthanide(III) Metals: Trends and Comparisons},
journal = {Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences},
year = {2008},
volume = {63},
publisher = {Walter de Gruyter},
month = {mar},
url = {https://www.degruyter.com/document/doi/10.1515/znb-2008-0307/html},
number = {3},
pages = {267--274},
doi = {10.1515/znb-2008-0307}
}
Cite this
MLA
Copy
Harder, Sjoerd, et al. “Benzyl Complexes of Lanthanide(II) and Lanthanide(III) Metals: Trends and Comparisons.” Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 63, no. 3, Mar. 2008, pp. 267-274. https://www.degruyter.com/document/doi/10.1515/znb-2008-0307/html.