Radiochimica Acta, volume 100, issue 6, pages 401-408
Increase in the specific radioactivity of tritium-labeled compounds obtained by tritium thermal activation method
Publication type: Journal Article
Publication date: 2012-01-10
Journal:
Radiochimica Acta
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 1.8
ISSN: 00338230, 21933405
Physical and Theoretical Chemistry
Abstract
A method of tritium introduction into different types of organic molecules that is based on the interaction of atomic tritium with solid organic target is described. Tritium atoms are formed on the hot W-wire, which is heated by the electric current. Such an approach is called “tritium thermal activation method”. Here we summarize the results of labeling globular proteins (lysozyme, human and bovine serum albumins); derivatives of pantothenic acid and amino acids; ionic surfactants (sodium dodecylsulfate and alkyltrimethylammonium bromides) and nonionic high-molecular weight surfactants – pluronics. For the first time it is observed that if the target-compound is fixed and its radicals are stable the specific radioactivity of the labeled product can be drastically increased (up to 400 times) when the target temperature is ca. 295 K compared with the results obtained at 77 K. The influence of labeling parameters as tritium gas pressure, exposure time and W-wire temperature was tested for each target temperature that results in the optimum labeling conditions with high specific radioactivity and chemical yield of the resulting compound.
Citations by journals
Citations by publishers
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5
10
15
20
25
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Elsevier
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Elsevier
21 publications, 40.38%
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Pleiades Publishing
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Pleiades Publishing
17 publications, 32.69%
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Springer Nature
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Springer Nature
4 publications, 7.69%
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Taylor & Francis
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Taylor & Francis
3 publications, 5.77%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 5.77%
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Wiley
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Wiley
1 publication, 1.92%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 1.92%
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Walter de Gruyter
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Walter de Gruyter
1 publication, 1.92%
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Trans Tech Publications
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Trans Tech Publications
1 publication, 1.92%
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5
10
15
20
25
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Badun G., Chernysheva M. G., Ksenofontov A. L. Increase in the specific radioactivity of tritium-labeled compounds obtained by tritium thermal activation method // Radiochimica Acta. 2012. Vol. 100. No. 6. pp. 401-408.
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Badun G., Chernysheva M. G., Ksenofontov A. L. Increase in the specific radioactivity of tritium-labeled compounds obtained by tritium thermal activation method // Radiochimica Acta. 2012. Vol. 100. No. 6. pp. 401-408.
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TY - JOUR
DO - 10.1524/ract.2012.1926
UR - https://doi.org/10.1524%2Fract.2012.1926
TI - Increase in the specific radioactivity of tritium-labeled compounds obtained by tritium thermal activation method
T2 - Radiochimica Acta
AU - Badun, G.A.
AU - Chernysheva, M G
AU - Ksenofontov, A. L.
PY - 2012
DA - 2012/01/10 00:00:00
PB - Walter de Gruyter
SP - 401-408
IS - 6
VL - 100
SN - 0033-8230
SN - 2193-3405
ER -
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@article{2012_Badun,
author = {G.A. Badun and M G Chernysheva and A. L. Ksenofontov},
title = {Increase in the specific radioactivity of tritium-labeled compounds obtained by tritium thermal activation method},
journal = {Radiochimica Acta},
year = {2012},
volume = {100},
publisher = {Walter de Gruyter},
month = {jan},
url = {https://doi.org/10.1524%2Fract.2012.1926},
number = {6},
pages = {401--408},
doi = {10.1524/ract.2012.1926}
}
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Badun, G.A., et al. “Increase in the specific radioactivity of tritium-labeled compounds obtained by tritium thermal activation method.” Radiochimica Acta, vol. 100, no. 6, Jan. 2012, pp. 401-408. https://doi.org/10.1524%2Fract.2012.1926.