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Synergistic solvent extraction of lanthanides(III) with mixtures of 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone and phosphoryl-containing podands
Publication type: Journal Article
Publication date: 2020-03-20
scimago Q3
wos Q3
SJR: 0.250
CiteScore: 2.4
Impact factor: 1.3
ISSN: 13180207, 15803155
PubMed ID:
33558939
Abstract
The solvent extraction of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu from weak acidic chloride solutions into an organic phase containing 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone (HP) and phosphoryl-containing podands (L) has been studied. A considerable synergistic effect was observed in the presence of neutral ligands L in the organic phase containing HP. The stoichiometry of the Ln(III) extracted species was determined by slope analysis and the equilibrium constants were calculated. It was found that the lanthanide(III) ions are extracted with mixtures of HP and neutral ligands in toluene from weak acidic solutions as LnLP3 complexes.
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Turanov А. N. et al. Synergistic solvent extraction of lanthanides(III) with mixtures of 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone and phosphoryl-containing podands // Acta Chimica Slovenica. 2020. Vol. 67. No. 1. pp. 246-252.
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Turanov А. N., Karandashev V. K., Baulin V. E., Baulin D. V., Tsivadze A. Y. Synergistic solvent extraction of lanthanides(III) with mixtures of 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone and phosphoryl-containing podands // Acta Chimica Slovenica. 2020. Vol. 67. No. 1. pp. 246-252.
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TY - JOUR
DO - 10.17344/acsi.2019.5380
UR - https://doi.org/10.17344/acsi.2019.5380
TI - Synergistic solvent extraction of lanthanides(III) with mixtures of 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone and phosphoryl-containing podands
T2 - Acta Chimica Slovenica
AU - Turanov, Аlexander Nikolaevich
AU - Karandashev, Vasilii Konstantinovich
AU - Baulin, Vladimir Evgenevich
AU - Baulin, Dmitriy Vladimirovich
AU - Tsivadze, Aslan Yusupovich
PY - 2020
DA - 2020/03/20
PB - Slovenian Chemical Society
SP - 246-252
IS - 1
VL - 67
PMID - 33558939
SN - 1318-0207
SN - 1580-3155
ER -
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@article{2020_Turanov,
author = {Аlexander Nikolaevich Turanov and Vasilii Konstantinovich Karandashev and Vladimir Evgenevich Baulin and Dmitriy Vladimirovich Baulin and Aslan Yusupovich Tsivadze},
title = {Synergistic solvent extraction of lanthanides(III) with mixtures of 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone and phosphoryl-containing podands},
journal = {Acta Chimica Slovenica},
year = {2020},
volume = {67},
publisher = {Slovenian Chemical Society},
month = {mar},
url = {https://doi.org/10.17344/acsi.2019.5380},
number = {1},
pages = {246--252},
doi = {10.17344/acsi.2019.5380}
}
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MLA
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Turanov, Аlexander Nikolaevich, et al. “Synergistic solvent extraction of lanthanides(III) with mixtures of 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone and phosphoryl-containing podands.” Acta Chimica Slovenica, vol. 67, no. 1, Mar. 2020, pp. 246-252. https://doi.org/10.17344/acsi.2019.5380.
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