Ionic liquid based on a quaternary phosphonium cation as a plasticizer and an electrode-active component of ion-selective electrode membranes
Publication type: Journal Article
Publication date: 2007-02-01
scimago Q4
wos Q4
SJR: 0.153
CiteScore: 1.1
Impact factor: 0.5
ISSN: 00271314, 19350260
General Chemistry
Abstract
The dodecylethyldiphenylphosphonium bis(trifluoromethylsulfonyl)imide ionic liquid (IL) can behave as both a plasticizer and an electrode-active component in the membranes of ion-selective electrodes (ISEs). A stable potentiometric response to cationic surfactants is observed. The slope of the electrode function is close to the Nernstian value for cetylpyridinium (CP) bromide and cetyltrimethylammonium (CTMA) bromide; the detection limits are (5.0 ± 1.0) × 10−6 and (1.3 ± 0.3) × 10−5 mol/l, respectively. The membrane potential does not depend on pH in the range from 3 to 11. The possibility of determining the critical micelle concentration (CMC) with the ISEs is demonstrated.
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Chernyshev D. V. et al. Ionic liquid based on a quaternary phosphonium cation as a plasticizer and an electrode-active component of ion-selective electrode membranes // Moscow University Chemistry Bulletin. 2007. Vol. 62. No. 1. pp. 48-51.
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Chernyshev D. V., Khrenova M. G., Pletnev I. V., Baulin V. E., Shvedene N. V. Ionic liquid based on a quaternary phosphonium cation as a plasticizer and an electrode-active component of ion-selective electrode membranes // Moscow University Chemistry Bulletin. 2007. Vol. 62. No. 1. pp. 48-51.
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TY - JOUR
DO - 10.3103/S0027131407010117
UR - http://link.springer.com/10.3103/S0027131407010117
TI - Ionic liquid based on a quaternary phosphonium cation as a plasticizer and an electrode-active component of ion-selective electrode membranes
T2 - Moscow University Chemistry Bulletin
AU - Chernyshev, D V
AU - Khrenova, M. G.
AU - Pletnev, I V
AU - Baulin, V E
AU - Shvedene, N V
PY - 2007
DA - 2007/02/01
PB - Allerton Press
SP - 48-51
IS - 1
VL - 62
SN - 0027-1314
SN - 1935-0260
ER -
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@article{2007_Chernyshev,
author = {D V Chernyshev and M. G. Khrenova and I V Pletnev and V E Baulin and N V Shvedene},
title = {Ionic liquid based on a quaternary phosphonium cation as a plasticizer and an electrode-active component of ion-selective electrode membranes},
journal = {Moscow University Chemistry Bulletin},
year = {2007},
volume = {62},
publisher = {Allerton Press},
month = {feb},
url = {http://link.springer.com/10.3103/S0027131407010117},
number = {1},
pages = {48--51},
doi = {10.3103/S0027131407010117}
}
Cite this
MLA
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Chernyshev, D. V., et al. “Ionic liquid based on a quaternary phosphonium cation as a plasticizer and an electrode-active component of ion-selective electrode membranes.” Moscow University Chemistry Bulletin, vol. 62, no. 1, Feb. 2007, pp. 48-51. http://link.springer.com/10.3103/S0027131407010117.
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