Oxidation of the polycrystalline gold foil surface and XPS study of oxygen states in oxide layers
Publication type: Journal Article
Publication date: 2007-12-01
scimago Q4
wos Q4
SJR: 0.153
CiteScore: 1.1
Impact factor: 0.5
ISSN: 00271314, 19350260
General Chemistry
Abstract
Gold oxide films obtained on the surface of polycrystalline gold foil upon oxidation by oxygen activated by a high-frequency discharge have been studied by X-ray photoelectron spectroscopy. High-frequency O2 activation affords oxide films more than 3–5 nm thick. As follows from Au4f spectra, the surface gold atoms are oxidized to the oxidation state +3. The O1s spectra have a composite shape and are decomposed into four components that characterize nonequivalent states of oxygen in the resulting oxide films. It is assumed that the two major oxygen states (E b(O1s) = 529.0 and 530.0 eV) correspond to the oxygen atoms in two-and three-dimensional gold oxide Au2O3, respectively. The oxygen states characterized by the higher binding energies (E b(O1s) = 531.8 and 535.2 eV) likely correspond to molecular oxygen in peroxide and superoxide groups, respectively.
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57
Total citations:
57
Citations from 2024:
8
(14%)
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Stadnichenko A. I., Koshcheev S., BORONIN A. Oxidation of the polycrystalline gold foil surface and XPS study of oxygen states in oxide layers // Moscow University Chemistry Bulletin. 2007. Vol. 62. No. 6. pp. 343-349.
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Stadnichenko A. I., Koshcheev S., BORONIN A. Oxidation of the polycrystalline gold foil surface and XPS study of oxygen states in oxide layers // Moscow University Chemistry Bulletin. 2007. Vol. 62. No. 6. pp. 343-349.
Cite this
RIS
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TY - JOUR
DO - 10.3103/S0027131407060090
UR - https://doi.org/10.3103/S0027131407060090
TI - Oxidation of the polycrystalline gold foil surface and XPS study of oxygen states in oxide layers
T2 - Moscow University Chemistry Bulletin
AU - Stadnichenko, A I
AU - Koshcheev, S.V
AU - BORONIN, A.I.
PY - 2007
DA - 2007/12/01
PB - Pleiades Publishing
SP - 343-349
IS - 6
VL - 62
SN - 0027-1314
SN - 1935-0260
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Stadnichenko,
author = {A I Stadnichenko and S.V Koshcheev and A.I. BORONIN},
title = {Oxidation of the polycrystalline gold foil surface and XPS study of oxygen states in oxide layers},
journal = {Moscow University Chemistry Bulletin},
year = {2007},
volume = {62},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.3103/S0027131407060090},
number = {6},
pages = {343--349},
doi = {10.3103/S0027131407060090}
}
Cite this
MLA
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Stadnichenko, A. I., et al. “Oxidation of the polycrystalline gold foil surface and XPS study of oxygen states in oxide layers.” Moscow University Chemistry Bulletin, vol. 62, no. 6, Dec. 2007, pp. 343-349. https://doi.org/10.3103/S0027131407060090.
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