The Russian Academy of Sciences
Журнал неорганической химии
,  том 69 ,  издание 3 ,  страницы 422-432

Phase Diagram and Metastable Phases in the LaPO4–YPO4–(H2O) System

Тип публикации: Journal Article
Дата публикации: 2024-09-05
The Russian Academy of Sciences
Включен в RSCI
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ISSN: 0044457X
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Phase formation in the LaPO4-YPO4-(H2O) system was studied under hydrothermal conditions at T≈230°C and after thermal treatment in the temperature range 1000–1400°C. The phase equilibrium diagram was constructed for the LaPO4-YPO4 system. The regions of metastable binodal and spinodal phase transition monazite-structured with a critical point Tcr = 931°C have been calculated. The experimentally determined eutectic temperature of 1850±35°C is in good agreement with the calculated value Te=1820°C. The maximum solubility of YPO4 in LaPO4 at eutectic temperature obtained from the thermodynamic optimized phase diagram is 50.5 mol.%.

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Enikeeva M. O. et al. Phase Diagram and Metastable Phases in the LaPO4–YPO4–(H2O) System // Журнал неорганической химии. 2024. Vol. 69. No. 3. pp. 422-432.
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Enikeeva M. O., Proskurina O. V., Gusarov V. V. Phase Diagram and Metastable Phases in the LaPO4–YPO4–(H2O) System // Журнал неорганической химии. 2024. Vol. 69. No. 3. pp. 422-432.
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TY - JOUR
DO - 10.31857/s0044457x24030161
UR - https://journals.rcsi.science/0044-457X/article/view/262896
TI - Phase Diagram and Metastable Phases in the LaPO4–YPO4–(H2O) System
T2 - Журнал неорганической химии
AU - Enikeeva, M O
AU - Proskurina, O V
AU - Gusarov, V V
PY - 2024
DA - 2024/09/05
PB - The Russian Academy of Sciences
SP - 422-432
IS - 3
VL - 69
SN - 0044-457X
ER -
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@article{2024_Enikeeva,
author = {M O Enikeeva and O V Proskurina and V V Gusarov},
title = {Phase Diagram and Metastable Phases in the LaPO4–YPO4–(H2O) System},
journal = {Журнал неорганической химии},
year = {2024},
volume = {69},
publisher = {The Russian Academy of Sciences},
month = {sep},
url = {https://journals.rcsi.science/0044-457X/article/view/262896},
number = {3},
pages = {422--432},
doi = {10.31857/s0044457x24030161}
}
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Enikeeva, M. O., et al. “Phase Diagram and Metastable Phases in the LaPO4–YPO4–(H2O) System.” Журнал неорганической химии, vol. 69, no. 3, Sep. 2024, pp. 422-432. https://journals.rcsi.science/0044-457X/article/view/262896.